Synthesis and properties of stable 2-metallanaphthalenes of heavier group 14 elements

Yoshiyuki Mizuhata, Takahiro Sasamori, Noriyoshi Nagahora, Yasuaki Watanabe, Yukio Furukawa, Norihiro Tokitoh

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The first stable neutral stannaaromatic compound, 2-stannanaphthalene 1a, was synthesized by taking advantage of an extremely bulky and efficient steric protection group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt). The molecular structure and aromaticity of 1a were discussed on the basis of X-ray crystallographic analysis, NMR, UV-vis, and Raman spectroscopy, cyclic voltammetry, and theoretical calculations. 2-Germanaphthalene 2a, which has a framework similar to that of 1a, was synthesized for comparison, and systematic elucidation was made for the properties of 2-metallanaphthalene systems containing a heavier group 14 element (Si, Ge, or Sn).

Original languageEnglish
Pages (from-to)4409-4418
Number of pages10
JournalDalton Transactions
Issue number33
DOIs
Publication statusPublished - 2008 Aug 20

ASJC Scopus subject areas

  • Inorganic Chemistry

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