Synthesis and reactions of a stable 1,2-diaryl-1,2-dibromodisilene: A precursor for substituted disilenes and a 1,2-diaryldisilyne

Takahiro Sasamori, Koji Hironaka, Yusuke Sugiyama, Nozomi Takagi, Shigeru Nagase, Yoshinobu Hosoi, Yukio Furukawa, Norihiro Tokitoh

Research output: Contribution to journalArticle

145 Citations (Scopus)

Abstract

Synthesis and isolation of the stable diaryldibromodisilene, Bbt(Br)Si-Si(Br)Bbt, has been accomplished for the first time. The dibromodisilene underwent substitution reactions with organometallic reagents on the low-coordinated silicon atom to afford the corresponding substituted disilenes. Furthermore, the reaction of 1 with t-BuLi afforded the corresponding 1,2-diaryldisilyne, BbtSi≡SiBbt, the characters of which were revealed by spectroscopic and crystallographic analyses.

Original languageEnglish
Pages (from-to)13856-13857
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number42
DOIs
Publication statusPublished - 2008 Oct 22

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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