Synthesis and spectroscopic properties of 1-azamkthanocyclopentacycloundecene ring systems

Makoto Nitta, Nobuhiro Kanomata, Masaru Tada

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Abstract

Novel 1-aza-6,11- and 1-aza-4,9-methnocyclopentacycloundecene ring systems were synthesized by the reaction of 3,8-methano[11]annulenone with N-(1-phenylvinylimino)triphenylphosphorane followed by dehydrogenation. These compounds are diatropic as 14pielectron vinylogues of 1-azaazulene.

Original languageEnglish
Pages (from-to)1291-1294
Number of pages4
JournalTetrahedron Letters
Volume31
Issue number9
DOIs
Publication statusPublished - 1990

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ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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