Abstract
We have investigated the structural sequence of BaxC7 binary systems. X-ray diffraction measurements revealed that there exist at least four stable phase at x=3, 4, 6, and 9. Among them, structural models are presented for BajC70 and Ba3C70. Ba3C70 takes an analogous structure to AlS-BajC, but the unit cell is distorted to tetragonal with the cell doubling. BagCyg is fee, involves a distorted cube of Ba8 in the octahedral interstices. This x=9 structure is also known in K.9C10 as a saturated phase.
| Original language | English |
|---|---|
| Pages (from-to) | 617-622 |
| Number of pages | 6 |
| Journal | Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals |
| Volume | 340 |
| Publication status | Published - 2000 |
| Externally published | Yes |
Keywords
- Co; intercalation chemistry
- Fullerene
- Structural sequence
ASJC Scopus subject areas
- Condensed Matter Physics
Fingerprint Dive into the research topics of 'Synthesis and structure of BaxC<sub>70</sub>'. Together they form a unique fingerprint.
Cite this
Takenobu, T., Chen, X., Iwasa, Y., & Mitani, T. (2000). Synthesis and structure of BaxC70
Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 340, 617-622.