Synthesis and structure of the first per-substituted anthracene host: Decakis(cyclopentylthio)anthracene

Christopher S. Frampton, William M. McGregor, David D. MacNicol, Paul R. Mallinson, Stuart J. Rowan, Raymond G. Plevey

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The title compound, a novel host molecule, has been prepared both from mixtures of unsaturated fluorocarbons related to perfluoroperhydroanthracene and, in an extension of a remarkable new reaction, perfluoroperhydroanthracene itself. The 1,4-dioxane inclusion compound of this anthracene-based host is triclinic, space group PI, with a=11.826(l), b=15.297(1), c=20.280(l) Å, α=98.77(1), β = 99.85(1), and γ = 95.83(1)°, with two host, and ca. three 1,4-dioxane guest molecules per unit cell. The host molecule occupies a general position in the unit cell and its anthracene core is markedly non-planar; each of the three crystallographically independent six-membered rings possesses a shallow twist-boat conformation. The host's side-chain moieties display an asymmetrical conformational distribution of the abbabaabab type (a = above, b = below, mean core plane).

Original languageEnglish
Pages (from-to)223-226
Number of pages4
JournalSupramolecular Chemistry
Volume3
Issue number3
DOIs
Publication statusPublished - 1994
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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    Frampton, C. S., McGregor, W. M., MacNicol, D. D., Mallinson, P. R., Rowan, S. J., & Plevey, R. G. (1994). Synthesis and structure of the first per-substituted anthracene host: Decakis(cyclopentylthio)anthracene. Supramolecular Chemistry, 3(3), 223-226. https://doi.org/10.1080/10610279408028919