Synthesis and thermal characteristics of poly(thioarylene)s by thermal polymerization

Eishun Tsuchida; Kimihisa Yamamoto; Kenji Miyatake

doi:10.1016/1381-5148(96)00028-4

Synthesis and thermal characteristics of poly(thioarylene)s by thermal polymerization

Eishun Tsuchida, Kimihisa Yamamoto, Kenji Miyatake

Graduate School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Thermal polymerization of bis[4-(4-bromophenylthio)phenyl] disulfide (I), bis[4-(4-bromophenyloxy)phenyl] disulfide (II) and bis[(4-(4-bromophenylsulfony)phenyloxy)phenyl] disulfide (III) was carried out at 250°C in diphenyl ether. The resulting poly(thioarylene)s show high crystallinity and high thermal stability. The blends and copolymers of poly(thioarylene) were also prepared, whose thermal properties were investigated by DSC measurements.

Original language	English
Pages (from-to)	269-277
Number of pages	9
Journal	Reactive and Functional Polymers
Volume	30
Issue number	1-3
DOIs	https://doi.org/10.1016/1381-5148(96)00028-4
Publication status	Published - 1996 Jun

Keywords

Diaryl disulfide
Poly(thioarylene)
PPS copolymer
Thermal polymerization

ASJC Scopus subject areas

Chemistry(all)
Environmental Chemistry
Biochemistry
Chemical Engineering(all)
Polymers and Plastics
Materials Chemistry

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title = "Synthesis and thermal characteristics of poly(thioarylene)s by thermal polymerization",

abstract = "Thermal polymerization of bis[4-(4-bromophenylthio)phenyl] disulfide (I), bis[4-(4-bromophenyloxy)phenyl] disulfide (II) and bis[(4-(4-bromophenylsulfony)phenyloxy)phenyl] disulfide (III) was carried out at 250°C in diphenyl ether. The resulting poly(thioarylene)s show high crystallinity and high thermal stability. The blends and copolymers of poly(thioarylene) were also prepared, whose thermal properties were investigated by DSC measurements.",

keywords = "Diaryl disulfide, Poly(thioarylene), PPS copolymer, Thermal polymerization",

author = "Eishun Tsuchida and Kimihisa Yamamoto and Kenji Miyatake",

year = "1996",

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doi = "10.1016/1381-5148(96)00028-4",

language = "English",

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journal = "Reactive and Functional Polymers",

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T1 - Synthesis and thermal characteristics of poly(thioarylene)s by thermal polymerization

AU - Tsuchida, Eishun

AU - Yamamoto, Kimihisa

AU - Miyatake, Kenji

PY - 1996/6

Y1 - 1996/6

N2 - Thermal polymerization of bis[4-(4-bromophenylthio)phenyl] disulfide (I), bis[4-(4-bromophenyloxy)phenyl] disulfide (II) and bis[(4-(4-bromophenylsulfony)phenyloxy)phenyl] disulfide (III) was carried out at 250°C in diphenyl ether. The resulting poly(thioarylene)s show high crystallinity and high thermal stability. The blends and copolymers of poly(thioarylene) were also prepared, whose thermal properties were investigated by DSC measurements.

AB - Thermal polymerization of bis[4-(4-bromophenylthio)phenyl] disulfide (I), bis[4-(4-bromophenyloxy)phenyl] disulfide (II) and bis[(4-(4-bromophenylsulfony)phenyloxy)phenyl] disulfide (III) was carried out at 250°C in diphenyl ether. The resulting poly(thioarylene)s show high crystallinity and high thermal stability. The blends and copolymers of poly(thioarylene) were also prepared, whose thermal properties were investigated by DSC measurements.

KW - Diaryl disulfide

KW - Poly(thioarylene)

KW - PPS copolymer

KW - Thermal polymerization

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