Synthesis and thermal characteristics of poly(thioarylene)s by thermal polymerization

Eishun Tsuchida, Kimihisa Yamamoto, Kenji Miyatake

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Thermal polymerization of bis[4-(4-bromophenylthio)phenyl] disulfide (I), bis[4-(4-bromophenyloxy)phenyl] disulfide (II) and bis[(4-(4-bromophenylsulfony)phenyloxy)phenyl] disulfide (III) was carried out at 250°C in diphenyl ether. The resulting poly(thioarylene)s show high crystallinity and high thermal stability. The blends and copolymers of poly(thioarylene) were also prepared, whose thermal properties were investigated by DSC measurements.

Original languageEnglish
Pages (from-to)269-277
Number of pages9
JournalReactive and Functional Polymers
Volume30
Issue number1-3
DOIs
Publication statusPublished - 1996 Jun

Keywords

  • Diaryl disulfide
  • Poly(thioarylene)
  • PPS copolymer
  • Thermal polymerization

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Biochemistry
  • Chemical Engineering(all)
  • Polymers and Plastics
  • Materials Chemistry

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