Synthesis and x-ray molecular structure analysis of some Au-Co, Au-Mn, and Hg-Co bonded compounds

K. Nunokawa; S. Onaka; T. Yamaguchi; M. Yaguchi; T. Tatematsu; S. Watase; M. Nakamoto; T. Ito

doi:10.1080/0095897021000036389

Synthesis and x-ray molecular structure analysis of some Au-Co, Au-Mn, and Hg-Co bonded compounds

K. Nunokawa, S. Onaka^*, T. Yamaguchi, M. Yaguchi, T. Tatematsu, S. Watase, M. Nakamoto, T. Ito

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The reaction of NaCo(CO)_4-x(PR₃)_x (x = 0,1) with Au(PR₃)Cl was examined in THF. The products were characterized by single crystal X-ray analysis and/or XPS spectroscopy. When the THF solution of NaCo(CO)_4-x(PR₃)_x which was in situ prepared by the reduction of the corresponding cobalt carbonyl dimer with Na amalgam was filtered, the main product was (R₃P)Au-Co(CO)₄ and (R₃P)Au-Co(CO)_4-x (PR₃)_x (x=1,2); phosphine migration from the Au to the Co site was observed for bulky phosphines during the recrystallization process. When the THF solution of NaCo(CO)_4-x(PR₃)_x was not filtered, the main product had the composition of M[Co(CO)₃(PR₃)]₂. The element M was clearly determined to be Hg by XPS spectroscopy. The reaction of NaMn(CO)₅ with Au(PR₃)Cl, however, afforded R₃PAu-Mn(CO)₅. The bonding parameters such as Au-M and Hg-Co bond-lengths were interpreted in terms of the electronic nature of the R group of the monodentate PR₃ ligand.

Original language	English
Pages (from-to)	1353-1364
Number of pages	12
Journal	Journal of Coordination Chemistry
Volume	55
Issue number	11
DOIs	https://doi.org/10.1080/0095897021000036389
Publication status	Published - 2002 Nov 1
Externally published	Yes

Keywords

Au-M bond
CF-substituted aryl phosphine
X-ray structure
XPS spectrum

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/0095897021000036389

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@article{c8a2d53bf24f4cdebd1f190ae81062f1,

title = "Synthesis and x-ray molecular structure analysis of some Au-Co, Au-Mn, and Hg-Co bonded compounds",

abstract = "The reaction of NaCo(CO)4-x(PR3)x (x = 0,1) with Au(PR3)Cl was examined in THF. The products were characterized by single crystal X-ray analysis and/or XPS spectroscopy. When the THF solution of NaCo(CO)4-x(PR3)x which was in situ prepared by the reduction of the corresponding cobalt carbonyl dimer with Na amalgam was filtered, the main product was (R3P)Au-Co(CO)4 and (R3P)Au-Co(CO)4-x (PR3)x (x=1,2); phosphine migration from the Au to the Co site was observed for bulky phosphines during the recrystallization process. When the THF solution of NaCo(CO)4-x(PR3)x was not filtered, the main product had the composition of M[Co(CO)3(PR3)]2. The element M was clearly determined to be Hg by XPS spectroscopy. The reaction of NaMn(CO)5 with Au(PR3)Cl, however, afforded R3PAu-Mn(CO)5. The bonding parameters such as Au-M and Hg-Co bond-lengths were interpreted in terms of the electronic nature of the R group of the monodentate PR3 ligand.",

keywords = "Au-M bond, CF-substituted aryl phosphine, X-ray structure, XPS spectrum",

author = "K. Nunokawa and S. Onaka and T. Yamaguchi and M. Yaguchi and T. Tatematsu and S. Watase and M. Nakamoto and T. Ito",

note = "Funding Information: This research was funded by Grants-in-Aid for Scientific research on Priority Area (No. 11136218, No. 12023221 {\textquoteleft}{\textquoteleft}Metal-assembled Complexes{\textquoteright}{\textquoteright}) from the Ministry of Education, Science, Sports and Culture, Japan.",

year = "2002",

month = nov,

day = "1",

doi = "10.1080/0095897021000036389",

language = "English",

volume = "55",

pages = "1353--1364",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "11",

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TY - JOUR

T1 - Synthesis and x-ray molecular structure analysis of some Au-Co, Au-Mn, and Hg-Co bonded compounds

AU - Nunokawa, K.

AU - Onaka, S.

AU - Yamaguchi, T.

AU - Yaguchi, M.

AU - Tatematsu, T.

AU - Watase, S.

AU - Nakamoto, M.

AU - Ito, T.

N1 - Funding Information: This research was funded by Grants-in-Aid for Scientific research on Priority Area (No. 11136218, No. 12023221 ‘‘Metal-assembled Complexes’’) from the Ministry of Education, Science, Sports and Culture, Japan.

PY - 2002/11/1

Y1 - 2002/11/1

N2 - The reaction of NaCo(CO)4-x(PR3)x (x = 0,1) with Au(PR3)Cl was examined in THF. The products were characterized by single crystal X-ray analysis and/or XPS spectroscopy. When the THF solution of NaCo(CO)4-x(PR3)x which was in situ prepared by the reduction of the corresponding cobalt carbonyl dimer with Na amalgam was filtered, the main product was (R3P)Au-Co(CO)4 and (R3P)Au-Co(CO)4-x (PR3)x (x=1,2); phosphine migration from the Au to the Co site was observed for bulky phosphines during the recrystallization process. When the THF solution of NaCo(CO)4-x(PR3)x was not filtered, the main product had the composition of M[Co(CO)3(PR3)]2. The element M was clearly determined to be Hg by XPS spectroscopy. The reaction of NaMn(CO)5 with Au(PR3)Cl, however, afforded R3PAu-Mn(CO)5. The bonding parameters such as Au-M and Hg-Co bond-lengths were interpreted in terms of the electronic nature of the R group of the monodentate PR3 ligand.

AB - The reaction of NaCo(CO)4-x(PR3)x (x = 0,1) with Au(PR3)Cl was examined in THF. The products were characterized by single crystal X-ray analysis and/or XPS spectroscopy. When the THF solution of NaCo(CO)4-x(PR3)x which was in situ prepared by the reduction of the corresponding cobalt carbonyl dimer with Na amalgam was filtered, the main product was (R3P)Au-Co(CO)4 and (R3P)Au-Co(CO)4-x (PR3)x (x=1,2); phosphine migration from the Au to the Co site was observed for bulky phosphines during the recrystallization process. When the THF solution of NaCo(CO)4-x(PR3)x was not filtered, the main product had the composition of M[Co(CO)3(PR3)]2. The element M was clearly determined to be Hg by XPS spectroscopy. The reaction of NaMn(CO)5 with Au(PR3)Cl, however, afforded R3PAu-Mn(CO)5. The bonding parameters such as Au-M and Hg-Co bond-lengths were interpreted in terms of the electronic nature of the R group of the monodentate PR3 ligand.

KW - Au-M bond

KW - CF-substituted aryl phosphine

KW - X-ray structure

KW - XPS spectrum

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U2 - 10.1080/0095897021000036389

DO - 10.1080/0095897021000036389

M3 - Article

AN - SCOPUS:0036830378

SN - 0095-8972

VL - 55

SP - 1353

EP - 1364

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 11

ER -

Synthesis and x-ray molecular structure analysis of some Au-Co, Au-Mn, and Hg-Co bonded compounds

Abstract

Keywords

ASJC Scopus subject areas

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