Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction

Shunsuke Sueki; Takeyuki Igarashi; Takayuki Nakajima; Isao Shimizu

doi:10.1246/cl.2006.682

Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction

Shunsuke Sueki, Takeyuki Igarashi, Takayuki Nakajima, Isao Shimizu

Waseda University

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

The direct-Mannich reaction of ketones 1, aldehydes 2, and anilines 3 was studied using catalytic amount of transition-metal complexes. The trivalent iridium complex, [IrCl₂(H)(COd)]₂, catalyzed the direct-Mannich reaction effectively to give various β-amino kenotes in good yields under mild conditions.

Original language	English
Pages (from-to)	682-683
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	6
DOIs	https://doi.org/10.1246/cl.2006.682
Publication status	Published - 2006 Jun 5

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.2006.682

Fingerprint Dive into the research topics of 'Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction'. Together they form a unique fingerprint.

Cite this

Sueki, S., Igarashi, T., Nakajima, T., & Shimizu, I. (2006). Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction. Chemistry Letters, 35(6), 682-683. https://doi.org/10.1246/cl.2006.682

@article{0471f31ee76245d68e12c0434b9e2c07,

title = "Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction",

abstract = "The direct-Mannich reaction of ketones 1, aldehydes 2, and anilines 3 was studied using catalytic amount of transition-metal complexes. The trivalent iridium complex, [IrCl2(H)(COd)]2, catalyzed the direct-Mannich reaction effectively to give various β-amino kenotes in good yields under mild conditions.",

author = "Shunsuke Sueki and Takeyuki Igarashi and Takayuki Nakajima and Isao Shimizu",

year = "2006",

month = jun,

day = "5",

doi = "10.1246/cl.2006.682",

language = "English",

volume = "35",

pages = "682--683",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "6",

}

TY - JOUR

T1 - Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction

AU - Sueki, Shunsuke

AU - Igarashi, Takeyuki

AU - Nakajima, Takayuki

AU - Shimizu, Isao

PY - 2006/6/5

Y1 - 2006/6/5

N2 - The direct-Mannich reaction of ketones 1, aldehydes 2, and anilines 3 was studied using catalytic amount of transition-metal complexes. The trivalent iridium complex, [IrCl2(H)(COd)]2, catalyzed the direct-Mannich reaction effectively to give various β-amino kenotes in good yields under mild conditions.

AB - The direct-Mannich reaction of ketones 1, aldehydes 2, and anilines 3 was studied using catalytic amount of transition-metal complexes. The trivalent iridium complex, [IrCl2(H)(COd)]2, catalyzed the direct-Mannich reaction effectively to give various β-amino kenotes in good yields under mild conditions.

UR - http://www.scopus.com/inward/record.url?scp=33748125680&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33748125680&partnerID=8YFLogxK

U2 - 10.1246/cl.2006.682

DO - 10.1246/cl.2006.682

M3 - Article

AN - SCOPUS:33748125680

VL - 35

SP - 682

EP - 683

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 6

ER -