Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction

Shunsuke Sueki, Takeyuki Igarashi, Takayuki Nakajima, Isao Shimizu

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The direct-Mannich reaction of ketones 1, aldehydes 2, and anilines 3 was studied using catalytic amount of transition-metal complexes. The trivalent iridium complex, [IrCl2(H)(COd)]2, catalyzed the direct-Mannich reaction effectively to give various β-amino kenotes in good yields under mild conditions.

Original languageEnglish
Pages (from-to)682-683
Number of pages2
JournalChemistry Letters
Volume35
Issue number6
DOIs
Publication statusPublished - 2006 Jun 5

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Aniline Compounds
Iridium
Coordination Complexes
Ketones
Aldehydes
Transition metals

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction. / Sueki, Shunsuke; Igarashi, Takeyuki; Nakajima, Takayuki; Shimizu, Isao.

In: Chemistry Letters, Vol. 35, No. 6, 05.06.2006, p. 682-683.

Research output: Contribution to journalArticle

Sueki, S, Igarashi, T, Nakajima, T & Shimizu, I 2006, 'Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction', Chemistry Letters, vol. 35, no. 6, pp. 682-683. https://doi.org/10.1246/cl.2006.682
Sueki, Shunsuke ; Igarashi, Takeyuki ; Nakajima, Takayuki ; Shimizu, Isao. / Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction. In: Chemistry Letters. 2006 ; Vol. 35, No. 6. pp. 682-683.
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