Synthesis of 1,1-organodiboronates via Rh(I)CI-catalyzed sequential regioselective hydroboration of 1-alkynes

Kohei Endo, Munenao Hirokami, Takanori Shibata

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

A Rh(I)Cl-DPPB-complex-catalyzed sequential hydroboration of aryl alkynes and aliphatic alkynes was achieved. The reaction proceeded with almost perfect regioselectivity to afford 1,1-organodiboronate compounds in moderate to good yield.

Original languageEnglish
Pages (from-to)1331-1335
Number of pages5
JournalSynlett
Issue number8
DOIs
Publication statusPublished - 2009 May 1

Keywords

  • Alkynes
  • Hydroborations
  • Regioselectivity
  • Rhodium

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Synthesis of 1,1-organodiboronates via Rh(I)CI-catalyzed sequential regioselective hydroboration of 1-alkynes'. Together they form a unique fingerprint.

  • Cite this