Synthesis of 1,1-organodiboronates via Rh(I)CI-catalyzed sequential regioselective hydroboration of 1-alkynes

Kohei Endo, Munenao Hirokami, Takanori Shibata

    Research output: Contribution to journalArticle

    46 Citations (Scopus)

    Abstract

    A Rh(I)Cl-DPPB-complex-catalyzed sequential hydroboration of aryl alkynes and aliphatic alkynes was achieved. The reaction proceeded with almost perfect regioselectivity to afford 1,1-organodiboronate compounds in moderate to good yield.

    Original languageEnglish
    Pages (from-to)1331-1335
    Number of pages5
    JournalSynlett
    Issue number8
    DOIs
    Publication statusPublished - 2009 May

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    Alkynes
    Regioselectivity

    Keywords

    • Alkynes
    • Hydroborations
    • Regioselectivity
    • Rhodium

    ASJC Scopus subject areas

    • Organic Chemistry

    Cite this

    Synthesis of 1,1-organodiboronates via Rh(I)CI-catalyzed sequential regioselective hydroboration of 1-alkynes. / Endo, Kohei; Hirokami, Munenao; Shibata, Takanori.

    In: Synlett, No. 8, 05.2009, p. 1331-1335.

    Research output: Contribution to journalArticle

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