Synthesis of a quadruply hydrogen bonded porphyrin supramolecular co-polymer and facilitated oxygen transport in its membrane

Satoshi Nakajima; Haruki Ohkawa; Hiroyuki Nishide

Synthesis of a quadruply hydrogen bonded porphyrin supramolecular co-polymer and facilitated oxygen transport in its membrane

Satoshi Nakajima^*, Haruki Ohkawa, Hiroyuki Nishide

^*Corresponding author for this work

Waseda Research Institute for Science and Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Ureidopyrimidinone forms a stable duplex via a self-complementary quandruple hydrogen bonding. A porphyrin with two UPy moieties was synthesized by the reaction with activated isocytosine. The Supramolecular co-polymer was prepared by simply mixing the co-monomers, namely, the telechelic UPy unit of the porphyrin and poly-(ethylene butylene). The free-standing membrane was able to be prepared in a wide-ranged comonomer composition. The facilitated oxygen transport capability of the membrane will be also reported in connection with its phase-segregated morphology and its composition.

Original language	English
Title of host publication	Polymer Preprints, Japan
Pages	2901
Number of pages	1
Volume	55
Edition	2
Publication status	Published - 2006
Event	55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama Duration: 2006 Sept 20 → 2006 Sept 22

Other

Other	55th Society of Polymer Science Japan Symposium on Macromolecules
City	Toyama
Period	06/9/20 → 06/9/22

Keywords

Facilitated transport membrane
Phase segregation
Porphyrin
Quadruple hydrogen bond
Supramolecular polymer

ASJC Scopus subject areas

Engineering(all)

Cite this

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title = "Synthesis of a quadruply hydrogen bonded porphyrin supramolecular co-polymer and facilitated oxygen transport in its membrane",

abstract = "Ureidopyrimidinone forms a stable duplex via a self-complementary quandruple hydrogen bonding. A porphyrin with two UPy moieties was synthesized by the reaction with activated isocytosine. The Supramolecular co-polymer was prepared by simply mixing the co-monomers, namely, the telechelic UPy unit of the porphyrin and poly-(ethylene butylene). The free-standing membrane was able to be prepared in a wide-ranged comonomer composition. The facilitated oxygen transport capability of the membrane will be also reported in connection with its phase-segregated morphology and its composition.",

keywords = "Facilitated transport membrane, Phase segregation, Porphyrin, Quadruple hydrogen bond, Supramolecular polymer",

author = "Satoshi Nakajima and Haruki Ohkawa and Hiroyuki Nishide",

year = "2006",

language = "English",

volume = "55",

pages = "2901",

booktitle = "Polymer Preprints, Japan",

edition = "2",

note = "55th Society of Polymer Science Japan Symposium on Macromolecules ; Conference date: 20-09-2006 Through 22-09-2006",

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TY - GEN

T1 - Synthesis of a quadruply hydrogen bonded porphyrin supramolecular co-polymer and facilitated oxygen transport in its membrane

AU - Nakajima, Satoshi

AU - Ohkawa, Haruki

AU - Nishide, Hiroyuki

PY - 2006

Y1 - 2006

N2 - Ureidopyrimidinone forms a stable duplex via a self-complementary quandruple hydrogen bonding. A porphyrin with two UPy moieties was synthesized by the reaction with activated isocytosine. The Supramolecular co-polymer was prepared by simply mixing the co-monomers, namely, the telechelic UPy unit of the porphyrin and poly-(ethylene butylene). The free-standing membrane was able to be prepared in a wide-ranged comonomer composition. The facilitated oxygen transport capability of the membrane will be also reported in connection with its phase-segregated morphology and its composition.

AB - Ureidopyrimidinone forms a stable duplex via a self-complementary quandruple hydrogen bonding. A porphyrin with two UPy moieties was synthesized by the reaction with activated isocytosine. The Supramolecular co-polymer was prepared by simply mixing the co-monomers, namely, the telechelic UPy unit of the porphyrin and poly-(ethylene butylene). The free-standing membrane was able to be prepared in a wide-ranged comonomer composition. The facilitated oxygen transport capability of the membrane will be also reported in connection with its phase-segregated morphology and its composition.

KW - Facilitated transport membrane

KW - Phase segregation

KW - Porphyrin

KW - Quadruple hydrogen bond

KW - Supramolecular polymer

UR - http://www.scopus.com/inward/record.url?scp=33846170868&partnerID=8YFLogxK

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M3 - Conference contribution

AN - SCOPUS:33846170868

VL - 55

SP - 2901

BT - Polymer Preprints, Japan

T2 - 55th Society of Polymer Science Japan Symposium on Macromolecules

Y2 - 20 September 2006 through 22 September 2006

ER -

Synthesis of a quadruply hydrogen bonded porphyrin supramolecular co-polymer and facilitated oxygen transport in its membrane

Abstract

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Keywords

ASJC Scopus subject areas

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