Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

Takahiro Sasamori; Michiyasu Sakagami; Masatoshi Niwa; Heisuke Sakai; Yukio Furukawa; Norihiro Tokitoh

doi:10.1039/c2cc33277a

Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

Takahiro Sasamori^*, Michiyasu Sakagami, Masatoshi Niwa, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d–π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive P=P π-bond was achieved by steric protection using two bulky ferrocenyl moieties.

Original language	English
Pages (from-to)	8562-8564
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	68
DOIs	https://doi.org/10.1039/c2cc33277a
Publication status	Published - 2012 Jul 30

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c2cc33277a

Cite this

@article{5e75ec778a1c40af83146b8b2b4f32b7,

title = "Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene",

abstract = "The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d–π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive P=P π-bond was achieved by steric protection using two bulky ferrocenyl moieties.",

author = "Takahiro Sasamori and Michiyasu Sakagami and Masatoshi Niwa and Heisuke Sakai and Yukio Furukawa and Norihiro Tokitoh",

year = "2012",

month = jul,

day = "30",

doi = "10.1039/c2cc33277a",

language = "English",

volume = "48",

pages = "8562--8564",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "68",

}

TY - JOUR

T1 - Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

AU - Sasamori, Takahiro

AU - Sakagami, Michiyasu

AU - Niwa, Masatoshi

AU - Sakai, Heisuke

AU - Furukawa, Yukio

AU - Tokitoh, Norihiro

PY - 2012/7/30

Y1 - 2012/7/30

N2 - The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d–π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive P=P π-bond was achieved by steric protection using two bulky ferrocenyl moieties.

AB - The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d–π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive P=P π-bond was achieved by steric protection using two bulky ferrocenyl moieties.

UR - http://www.scopus.com/inward/record.url?scp=84864485599&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84864485599&partnerID=8YFLogxK

U2 - 10.1039/c2cc33277a

DO - 10.1039/c2cc33277a

M3 - Article

C2 - 22801589

AN - SCOPUS:84864485599

SN - 1359-7345

VL - 48

SP - 8562

EP - 8564

JO - Chemical Communications

JF - Chemical Communications

IS - 68

ER -

Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this