Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene

Takahiro Sasamori, Michiyasu Sakagami, Masatoshi Niwa, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh

    Research output: Contribution to journalArticle

    14 Citations (Scopus)

    Abstract

    The synthesis and characterization of a stable 1,2-bis(ferrocenyl) diphosphene, wherein a PP π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d-π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive PP π-bond was achieved by steric protection using two bulky ferrocenyl moieties.

    Original languageEnglish
    Pages (from-to)8562-8564
    Number of pages3
    JournalChemical Communications
    Volume48
    Issue number68
    DOIs
    Publication statusPublished - 2012 Sep 4

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    Stabilization
    Electrons

    ASJC Scopus subject areas

    • Metals and Alloys
    • Materials Chemistry
    • Surfaces, Coatings and Films
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Catalysis
    • Chemistry(all)

    Cite this

    Sasamori, T., Sakagami, M., Niwa, M., Sakai, H., Furukawa, Y., & Tokitoh, N. (2012). Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene. Chemical Communications, 48(68), 8562-8564. https://doi.org/10.1039/c2cc33277a

    Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene. / Sasamori, Takahiro; Sakagami, Michiyasu; Niwa, Masatoshi; Sakai, Heisuke; Furukawa, Yukio; Tokitoh, Norihiro.

    In: Chemical Communications, Vol. 48, No. 68, 04.09.2012, p. 8562-8564.

    Research output: Contribution to journalArticle

    Sasamori, T, Sakagami, M, Niwa, M, Sakai, H, Furukawa, Y & Tokitoh, N 2012, 'Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene', Chemical Communications, vol. 48, no. 68, pp. 8562-8564. https://doi.org/10.1039/c2cc33277a
    Sasamori T, Sakagami M, Niwa M, Sakai H, Furukawa Y, Tokitoh N. Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene. Chemical Communications. 2012 Sep 4;48(68):8562-8564. https://doi.org/10.1039/c2cc33277a
    Sasamori, Takahiro ; Sakagami, Michiyasu ; Niwa, Masatoshi ; Sakai, Heisuke ; Furukawa, Yukio ; Tokitoh, Norihiro. / Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene. In: Chemical Communications. 2012 ; Vol. 48, No. 68. pp. 8562-8564.
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