Synthesis of cobalt complex using pyrrole derivative with basic ligand and application to cathodic catalyst for oxygen reduction

Hidenori Murata, Yuichi Iai, Takahisa Otake, Kenichi Oyaizu, Kozo Kozawa, Makoto Yuasa

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A ligand compound with strong coordinating property, 2-(1H-pyrrole-3-yl) pyrazine (pz-Py), was synthesized to increase the density of active sites for oxygen reduction. The obtained compound was coordinated with cobalt (II) ions strongly. It was revealed that the metal complex could be used as a cathode catalyst in fuel cells. The potential for oxygen reduction was positive (E p = 0.27 V vs SCE) for the catalyst prepared by refluxing the corresponding compound, cobalt acetate tetrahydrate, and the carbon particles. This activity was superior to CoPy/C which was synthesized by refluxing pyrrole, cobalt acetate tetrahydrate, and the carbon particles, and it was shown that nitrogen atoms of pyrazine type contribute accumulation of cobalt ions. The activity of the catalyst was improved after heat treatment under Ar gas. These results show the potential use of the present catalyst as a novel cathode catalyst in fuel cells.

Original languageEnglish
Pages (from-to)964-968
Number of pages5
JournalElectrochemistry
Volume75
Issue number12
Publication statusPublished - 2007 Dec
Externally publishedYes

Fingerprint

Pyrroles
Cobalt
Ligands
Oxygen
Derivatives
Catalysts
Pyrazines
Fuel cells
Acetates
Cathodes
Carbon
Cobalt compounds
Ions
Coordination Complexes
Metal complexes
Nitrogen
Gases
Heat treatment
Atoms

Keywords

  • Basic ligand
  • Cathode catalyst
  • Fuel cells
  • Pyrrole

ASJC Scopus subject areas

  • Electrochemistry

Cite this

Synthesis of cobalt complex using pyrrole derivative with basic ligand and application to cathodic catalyst for oxygen reduction. / Murata, Hidenori; Iai, Yuichi; Otake, Takahisa; Oyaizu, Kenichi; Kozawa, Kozo; Yuasa, Makoto.

In: Electrochemistry, Vol. 75, No. 12, 12.2007, p. 964-968.

Research output: Contribution to journalArticle

Murata, Hidenori ; Iai, Yuichi ; Otake, Takahisa ; Oyaizu, Kenichi ; Kozawa, Kozo ; Yuasa, Makoto. / Synthesis of cobalt complex using pyrrole derivative with basic ligand and application to cathodic catalyst for oxygen reduction. In: Electrochemistry. 2007 ; Vol. 75, No. 12. pp. 964-968.
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