Synthesis of complex perovskite oxides via nanosheets process

Keigo Inaba, Shinya Suzuki, Yuji Noguchi, Masaru Miyayama, Minoru Osada

Research output: Contribution to journalArticle

Abstract

Complex perovskite oxides of Sr0.5(Nb0.5Ta 0.5)O3 were synthesized by reassembling (SrNb 2O7)2- and (Sr1.5Ta 3O10)2- nanosheets followed by topochemical dehydration with heat treatment. Atomic force microscopy (AFM) images showed that the thicknesses of the (SrNb2O7)2- and (Sr1.5Ta3O10)2- nanosheets were approximately 6 nm (7 unit layers) and 4 nm (3 unit layers), respectively. Raman scattering measurement has suggested that nanosheet-processed Sr 0.5(Nb0.5Ta0.5)O3 with B-site-cation ordering has a superlattice-like structure composed of alternating layers of Sr0.5NbO3 and Sr0.5TaO3 along the c-axis. Nanosheet-processed Sr0.5(Nb0.5Ta 0.5)O3 with B-site-cation ordering exhibited a dielectric permittivity of 42 (1 MHz), which was lower than that of solid-state-reacted samples (65) with disordered B-site cations.

Original languageEnglish
Pages (from-to)55-58
Number of pages4
JournalKey Engineering Materials
Volume350
DOIs
Publication statusPublished - 2007
Externally publishedYes

Keywords

  • Complex perovskite oxides
  • Dielectric permittivity
  • Nanosheets
  • Reassembled material

ASJC Scopus subject areas

  • Ceramics and Composites
  • Chemical Engineering (miscellaneous)

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