Abstract
Complex perovskite oxides of Sr0.5(Nb0.5Ta 0.5)O3 were synthesized by reassembling (SrNb 2O7)2- and (Sr1.5Ta 3O10)2- nanosheets followed by topochemical dehydration with heat treatment. Atomic force microscopy (AFM) images showed that the thicknesses of the (SrNb2O7)2- and (Sr1.5Ta3O10)2- nanosheets were approximately 6 nm (7 unit layers) and 4 nm (3 unit layers), respectively. Raman scattering measurement has suggested that nanosheet-processed Sr 0.5(Nb0.5Ta0.5)O3 with B-site-cation ordering has a superlattice-like structure composed of alternating layers of Sr0.5NbO3 and Sr0.5TaO3 along the c-axis. Nanosheet-processed Sr0.5(Nb0.5Ta 0.5)O3 with B-site-cation ordering exhibited a dielectric permittivity of 42 (1 MHz), which was lower than that of solid-state-reacted samples (65) with disordered B-site cations.
Original language | English |
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Pages (from-to) | 55-58 |
Number of pages | 4 |
Journal | Key Engineering Materials |
Volume | 350 |
DOIs | |
Publication status | Published - 2007 |
Externally published | Yes |
Keywords
- Complex perovskite oxides
- Dielectric permittivity
- Nanosheets
- Reassembled material
ASJC Scopus subject areas
- Ceramics and Composites
- Chemical Engineering (miscellaneous)