Synthesis of diphenylnitroxide-substituted polystyrenes and their p- and n-type redox property

Masashi Fujinaga, Takeo Suga, Hiroyuki Nishide

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Diphenylnitroxide derivatives are known to their high radical stability and stable redox properties suitable as an electrode-active material of the next generation secondary battery. A series of p, p'-disubstituted diphenylnitroxide derivatives were synthesized, and p-substituent effect on their redox properties were investigated by electrochemical measurements. Styrene derivative bearing the diphenylnitroxide radical was synthesized via 4 steps, and polymerized to give the precursor polymer (Mn =3.2 × 103). Chemical oxidation of this polymer yielded the corresponding radical polymer. Its redox behavior will be also reported.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages3981
Number of pages1
Volume55
Edition2
Publication statusPublished - 2006
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama
Duration: 2006 Sep 202006 Sep 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CityToyama
Period06/9/2006/9/22

Fingerprint

Polystyrenes
Derivatives
Polymers
Bearings (structural)
Secondary batteries
Styrene
Oxidation
Electrodes
Oxidation-Reduction

Keywords

  • Electrode-active material
  • Polystyrene derivative
  • Radical polymerization
  • Secondary battery

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Synthesis of diphenylnitroxide-substituted polystyrenes and their p- and n-type redox property. / Fujinaga, Masashi; Suga, Takeo; Nishide, Hiroyuki.

Polymer Preprints, Japan. Vol. 55 2. ed. 2006. p. 3981.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Fujinaga, M, Suga, T & Nishide, H 2006, Synthesis of diphenylnitroxide-substituted polystyrenes and their p- and n-type redox property. in Polymer Preprints, Japan. 2 edn, vol. 55, pp. 3981, 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, 06/9/20.
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