TY - JOUR
T1 - Synthesis of layered polysilicic acid-acrylamide intercalation compounds and polymerization in the interlayer spaces
AU - Yanagisawa, T.
AU - Yokoyama, C.
AU - Kuroda, K.
AU - Kato, C.
N1 - Copyright:
Copyright 2007 Elsevier B.V., All rights reserved.
PY - 1990
Y1 - 1990
N2 - Layered polysilicic acid-arylamide intercalation compounds were synthesized by the reaction of H-magadiite (H2Si14O29.xH2O) and H-kenyaite (H2Si20O41.xH2O) with acrylamide saturated aqueous solutions. The formation of the intercalation compounds were ascertained by X-ray powder diffraction, IR, 13C-CP MAS NMR, DTA, and chemical analysis. However, when H-magadiite was used, a part of the intercalated acrylamide molecules was oligomerized during the intercalation. A heat treatment of the layered polysilicic acid-acrylamide intercalation compounds led to a polymerization of the acrylamide in the interlayer spaces.
AB - Layered polysilicic acid-arylamide intercalation compounds were synthesized by the reaction of H-magadiite (H2Si14O29.xH2O) and H-kenyaite (H2Si20O41.xH2O) with acrylamide saturated aqueous solutions. The formation of the intercalation compounds were ascertained by X-ray powder diffraction, IR, 13C-CP MAS NMR, DTA, and chemical analysis. However, when H-magadiite was used, a part of the intercalated acrylamide molecules was oligomerized during the intercalation. A heat treatment of the layered polysilicic acid-acrylamide intercalation compounds led to a polymerization of the acrylamide in the interlayer spaces.
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U2 - 10.1246/bcsj.63.47
DO - 10.1246/bcsj.63.47
M3 - Article
AN - SCOPUS:0025375182
SN - 0009-2673
VL - 63
SP - 47
EP - 50
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 1
ER -