Synthesis of layered polysilicic acid-acrylamide intercalation compounds and polymerization in the interlayer spaces

T. Yanagisawa, C. Yokoyama, Kazuyuki Kuroda, C. Kato

    Research output: Contribution to journalArticle

    21 Citations (Scopus)

    Abstract

    Layered polysilicic acid-arylamide intercalation compounds were synthesized by the reaction of H-magadiite (H2Si14O29.xH2O) and H-kenyaite (H2Si20O41.xH2O) with acrylamide saturated aqueous solutions. The formation of the intercalation compounds were ascertained by X-ray powder diffraction, IR, 13C-CP MAS NMR, DTA, and chemical analysis. However, when H-magadiite was used, a part of the intercalated acrylamide molecules was oligomerized during the intercalation. A heat treatment of the layered polysilicic acid-acrylamide intercalation compounds led to a polymerization of the acrylamide in the interlayer spaces.

    Original languageEnglish
    Pages (from-to)47-50
    Number of pages4
    JournalBulletin of the Chemical Society of Japan
    Volume63
    Issue number1
    DOIs
    Publication statusPublished - 1990

    Fingerprint

    Intercalation compounds
    Acrylamide
    Polymerization
    Acids
    Intercalation
    X ray powder diffraction
    Differential thermal analysis
    Heat treatment
    Nuclear magnetic resonance
    Molecules
    Chemical analysis

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Synthesis of layered polysilicic acid-acrylamide intercalation compounds and polymerization in the interlayer spaces. / Yanagisawa, T.; Yokoyama, C.; Kuroda, Kazuyuki; Kato, C.

    In: Bulletin of the Chemical Society of Japan, Vol. 63, No. 1, 1990, p. 47-50.

    Research output: Contribution to journalArticle

    @article{fb786e9b92424159a7bea4305a94122a,
    title = "Synthesis of layered polysilicic acid-acrylamide intercalation compounds and polymerization in the interlayer spaces",
    abstract = "Layered polysilicic acid-arylamide intercalation compounds were synthesized by the reaction of H-magadiite (H2Si14O29.xH2O) and H-kenyaite (H2Si20O41.xH2O) with acrylamide saturated aqueous solutions. The formation of the intercalation compounds were ascertained by X-ray powder diffraction, IR, 13C-CP MAS NMR, DTA, and chemical analysis. However, when H-magadiite was used, a part of the intercalated acrylamide molecules was oligomerized during the intercalation. A heat treatment of the layered polysilicic acid-acrylamide intercalation compounds led to a polymerization of the acrylamide in the interlayer spaces.",
    author = "T. Yanagisawa and C. Yokoyama and Kazuyuki Kuroda and C. Kato",
    year = "1990",
    doi = "10.1246/bcsj.63.47",
    language = "English",
    volume = "63",
    pages = "47--50",
    journal = "Bulletin of the Chemical Society of Japan",
    issn = "0009-2673",
    publisher = "Chemical Society of Japan",
    number = "1",

    }

    TY - JOUR

    T1 - Synthesis of layered polysilicic acid-acrylamide intercalation compounds and polymerization in the interlayer spaces

    AU - Yanagisawa, T.

    AU - Yokoyama, C.

    AU - Kuroda, Kazuyuki

    AU - Kato, C.

    PY - 1990

    Y1 - 1990

    N2 - Layered polysilicic acid-arylamide intercalation compounds were synthesized by the reaction of H-magadiite (H2Si14O29.xH2O) and H-kenyaite (H2Si20O41.xH2O) with acrylamide saturated aqueous solutions. The formation of the intercalation compounds were ascertained by X-ray powder diffraction, IR, 13C-CP MAS NMR, DTA, and chemical analysis. However, when H-magadiite was used, a part of the intercalated acrylamide molecules was oligomerized during the intercalation. A heat treatment of the layered polysilicic acid-acrylamide intercalation compounds led to a polymerization of the acrylamide in the interlayer spaces.

    AB - Layered polysilicic acid-arylamide intercalation compounds were synthesized by the reaction of H-magadiite (H2Si14O29.xH2O) and H-kenyaite (H2Si20O41.xH2O) with acrylamide saturated aqueous solutions. The formation of the intercalation compounds were ascertained by X-ray powder diffraction, IR, 13C-CP MAS NMR, DTA, and chemical analysis. However, when H-magadiite was used, a part of the intercalated acrylamide molecules was oligomerized during the intercalation. A heat treatment of the layered polysilicic acid-acrylamide intercalation compounds led to a polymerization of the acrylamide in the interlayer spaces.

    UR - http://www.scopus.com/inward/record.url?scp=0025375182&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=0025375182&partnerID=8YFLogxK

    U2 - 10.1246/bcsj.63.47

    DO - 10.1246/bcsj.63.47

    M3 - Article

    VL - 63

    SP - 47

    EP - 50

    JO - Bulletin of the Chemical Society of Japan

    JF - Bulletin of the Chemical Society of Japan

    SN - 0009-2673

    IS - 1

    ER -