Synthesis of nitroxide-substituted polystyrene and its n-type redox property

Shinji Kasatori, Takeo Suga, Hiroyuki Nishide

Research output: Contribution to conferencePaperpeer-review

Abstract

The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.

Original languageEnglish
Number of pages1
Publication statusPublished - 2005 Dec 1
Event54th SPSJ Symposium on Macromolecules - Yamagata, Japan
Duration: 2005 Sep 202005 Sep 22

Other

Other54th SPSJ Symposium on Macromolecules
CountryJapan
CityYamagata
Period05/9/2005/9/22

Keywords

  • Electrode-active material
  • Nitroxide radical
  • Radical Polymer
  • Redox property

ASJC Scopus subject areas

  • Engineering(all)

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