Synthesis of nitroxide-substituted polystyrene and its n-type redox property

Shinji Kasatori, Takeo Suga, Hiroyuki Nishide

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The nitroxide radical is expected as an electrode active material of secondary battery. We synthesized polystyrene derivatives bearing nitroxide radical and investigated their electrochemical properties. Styrene monomer was synthesized from 5-bromo-2-aminobenzotrifluoride via four step reactions. The obtained styrene monomer was polymerized by radical polymerization and oxidized to its radical derivative. Electrochemical property of the radical polymer was examined by cyclic voltammetry. The formal potential was -0.76 V.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages4109
Number of pages1
Volume54
Edition2
Publication statusPublished - 2005
Event54th SPSJ Symposium on Macromolecules - Yamagata
Duration: 2005 Sep 202005 Sep 22

Other

Other54th SPSJ Symposium on Macromolecules
CityYamagata
Period05/9/2005/9/22

Fingerprint

Electrochemical properties
Styrene
Polystyrenes
Bearings (structural)
Monomers
Derivatives
Secondary batteries
Free radical polymerization
Cyclic voltammetry
Electrodes
Polymers
Oxidation-Reduction

Keywords

  • Electrode-active material
  • Nitroxide radical
  • Radical Polymer
  • Redox property

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Kasatori, S., Suga, T., & Nishide, H. (2005). Synthesis of nitroxide-substituted polystyrene and its n-type redox property. In Polymer Preprints, Japan (2 ed., Vol. 54, pp. 4109)

Synthesis of nitroxide-substituted polystyrene and its n-type redox property. / Kasatori, Shinji; Suga, Takeo; Nishide, Hiroyuki.

Polymer Preprints, Japan. Vol. 54 2. ed. 2005. p. 4109.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Kasatori, S, Suga, T & Nishide, H 2005, Synthesis of nitroxide-substituted polystyrene and its n-type redox property. in Polymer Preprints, Japan. 2 edn, vol. 54, pp. 4109, 54th SPSJ Symposium on Macromolecules, Yamagata, 05/9/20.
Kasatori S, Suga T, Nishide H. Synthesis of nitroxide-substituted polystyrene and its n-type redox property. In Polymer Preprints, Japan. 2 ed. Vol. 54. 2005. p. 4109
Kasatori, Shinji ; Suga, Takeo ; Nishide, Hiroyuki. / Synthesis of nitroxide-substituted polystyrene and its n-type redox property. Polymer Preprints, Japan. Vol. 54 2. ed. 2005. pp. 4109
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