SYNTHESIS OF OLIGO (PHENYLENEOXIDE) BY ELECTRO-OXIDATIVE POLYMERIZATION.

E. Tsuchida, Hiroyuki Nishide, T. Maekawa

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Anodic oxidation of 2,6-disubstituted phenols gave poly(2,6-disubstituted-1,4-phenyleneoxide)s quantitatively by using dichloromethane and tetraethyl ammonium bromide as the solvent and the supporting electrolyte respectively. Phenol was also electro-oxidatively polymerized to yield oligo(1,4-phenyleneoxide) with molecular weight of 1200 approx. 2500. The 2-step polymerization and the polymerization in the presence of bisphenol were carried out to increase the molecular weight of the oligo(phenyleneoxide). The mechanism of the electro-oxidative polymerization was discussed by electrochemical and ESR measurements.

Original languageEnglish
Pages (from-to)1081-1096
Number of pages16
JournalJournal of macromolecular science. Chemistry
VolumeA21
Issue number8-9
Publication statusPublished - 1983 Jul

ASJC Scopus subject areas

  • Engineering(all)

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