Synthesis of oligo(2,3,5.6-tetramethylphenylene selenide)

Eishun Tsuchida, Mistsutoshi Jikei, Kenji Miyatake, Kimihisa Yamamoto, Hiroyuki Nishide

Research output: Contribution to journalArticle

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Abstract

It has been reported that poly(p-phenylene sulfide) (PPS) and poly(p-phenylene selenide) (PPSe) show high electrical conductivity more than once after doping with acceptor molecules, such as AsF5 .1-3 Much attention is also paid to oligo(phenylene selenide) (OPSe) on the conductivity and photoconductivity, as well as those of PPSe. PPSe is usually prepared from p-dichlorobenzene and sodium selenide or the metal salt of p-halo-substituted benzeneselenol under high temperature and high pressure. This paper describes the synthesis of OPSe's with electron-donating substituents through oxidation.

Original languageEnglish
Pages (from-to)4732-4733
Number of pages2
JournalMacromolecules
Volume26
Issue number17
Publication statusPublished - 1993 Jan 1

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Photoconductivity
Sodium
Doping (additives)
Salts
Oxidation
Molecules
Electrons
Sulfides
Metals
Temperature
Electric Conductivity
poly-para-phenylene
4-dichlorobenzene
benzeneselenol
sodium selenide
arsenic pentafluoride

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Tsuchida, E., Jikei, M., Miyatake, K., Yamamoto, K., & Nishide, H. (1993). Synthesis of oligo(2,3,5.6-tetramethylphenylene selenide). Macromolecules, 26(17), 4732-4733.

Synthesis of oligo(2,3,5.6-tetramethylphenylene selenide). / Tsuchida, Eishun; Jikei, Mistsutoshi; Miyatake, Kenji; Yamamoto, Kimihisa; Nishide, Hiroyuki.

In: Macromolecules, Vol. 26, No. 17, 01.01.1993, p. 4732-4733.

Research output: Contribution to journalArticle

Tsuchida, E, Jikei, M, Miyatake, K, Yamamoto, K & Nishide, H 1993, 'Synthesis of oligo(2,3,5.6-tetramethylphenylene selenide)', Macromolecules, vol. 26, no. 17, pp. 4732-4733.
Tsuchida E, Jikei M, Miyatake K, Yamamoto K, Nishide H. Synthesis of oligo(2,3,5.6-tetramethylphenylene selenide). Macromolecules. 1993 Jan 1;26(17):4732-4733.
Tsuchida, Eishun ; Jikei, Mistsutoshi ; Miyatake, Kenji ; Yamamoto, Kimihisa ; Nishide, Hiroyuki. / Synthesis of oligo(2,3,5.6-tetramethylphenylene selenide). In: Macromolecules. 1993 ; Vol. 26, No. 17. pp. 4732-4733.
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