Synthesis of Poly(ethynylplatinumporphyrin) and its Application as an Oxygen Pressure-Sensitive Paint

Hyundae Hah, Tomoyuki Sakai, Keisuke Asai, Hiroyuki Nishide

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

5-(4-Trimethylsilyethynylphenyl)-10,15,20-triphenylplatinumporphyrin was synthesized and copolymerized with trimethylsilylpropyne to give a new high-molecular-weight porphyrin polymer. The polymer formed a smooth and tough coating on many types of surfaces. The coating showed a strong blue luminescence from the platinumporphyrin residue which was quenched in the presence of oxygen. The relationship of the luminescence intensity vs oxygen pressure displayed a remarkably high pressure sensitivity in the low oxygen pressure area, which was ascribed to the high oxygen permeability of the polymer.

Original languageEnglish
Pages (from-to)27-35
Number of pages9
JournalMacromolecular Symposia
Volume204
DOIs
Publication statusPublished - 2003 Nov

Fingerprint

pressure sensitive paints
Paint
Oxygen
Polymers
oxygen
synthesis
Luminescence
polymers
luminescence
coatings
Coatings
Porphyrins
porphyrins
molecular weight
permeability
Molecular weight

Keywords

  • Luminescence quenching
  • Metalloporphyrin
  • Poly(trimethylsilylpropyne)
  • Trace analysis for oxygen

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

Synthesis of Poly(ethynylplatinumporphyrin) and its Application as an Oxygen Pressure-Sensitive Paint. / Hah, Hyundae; Sakai, Tomoyuki; Asai, Keisuke; Nishide, Hiroyuki.

In: Macromolecular Symposia, Vol. 204, 11.2003, p. 27-35.

Research output: Contribution to journalArticle

@article{8ef0adcbe43a41cea785d2be6f310fe0,
title = "Synthesis of Poly(ethynylplatinumporphyrin) and its Application as an Oxygen Pressure-Sensitive Paint",
abstract = "5-(4-Trimethylsilyethynylphenyl)-10,15,20-triphenylplatinumporphyrin was synthesized and copolymerized with trimethylsilylpropyne to give a new high-molecular-weight porphyrin polymer. The polymer formed a smooth and tough coating on many types of surfaces. The coating showed a strong blue luminescence from the platinumporphyrin residue which was quenched in the presence of oxygen. The relationship of the luminescence intensity vs oxygen pressure displayed a remarkably high pressure sensitivity in the low oxygen pressure area, which was ascribed to the high oxygen permeability of the polymer.",
keywords = "Luminescence quenching, Metalloporphyrin, Poly(trimethylsilylpropyne), Trace analysis for oxygen",
author = "Hyundae Hah and Tomoyuki Sakai and Keisuke Asai and Hiroyuki Nishide",
year = "2003",
month = "11",
doi = "10.1002/masy.200351404",
language = "English",
volume = "204",
pages = "27--35",
journal = "Macromolecular Symposia",
issn = "1022-1360",
publisher = "Wiley-VCH Verlag",

}

TY - JOUR

T1 - Synthesis of Poly(ethynylplatinumporphyrin) and its Application as an Oxygen Pressure-Sensitive Paint

AU - Hah, Hyundae

AU - Sakai, Tomoyuki

AU - Asai, Keisuke

AU - Nishide, Hiroyuki

PY - 2003/11

Y1 - 2003/11

N2 - 5-(4-Trimethylsilyethynylphenyl)-10,15,20-triphenylplatinumporphyrin was synthesized and copolymerized with trimethylsilylpropyne to give a new high-molecular-weight porphyrin polymer. The polymer formed a smooth and tough coating on many types of surfaces. The coating showed a strong blue luminescence from the platinumporphyrin residue which was quenched in the presence of oxygen. The relationship of the luminescence intensity vs oxygen pressure displayed a remarkably high pressure sensitivity in the low oxygen pressure area, which was ascribed to the high oxygen permeability of the polymer.

AB - 5-(4-Trimethylsilyethynylphenyl)-10,15,20-triphenylplatinumporphyrin was synthesized and copolymerized with trimethylsilylpropyne to give a new high-molecular-weight porphyrin polymer. The polymer formed a smooth and tough coating on many types of surfaces. The coating showed a strong blue luminescence from the platinumporphyrin residue which was quenched in the presence of oxygen. The relationship of the luminescence intensity vs oxygen pressure displayed a remarkably high pressure sensitivity in the low oxygen pressure area, which was ascribed to the high oxygen permeability of the polymer.

KW - Luminescence quenching

KW - Metalloporphyrin

KW - Poly(trimethylsilylpropyne)

KW - Trace analysis for oxygen

UR - http://www.scopus.com/inward/record.url?scp=0347362635&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0347362635&partnerID=8YFLogxK

U2 - 10.1002/masy.200351404

DO - 10.1002/masy.200351404

M3 - Article

AN - SCOPUS:0347362635

VL - 204

SP - 27

EP - 35

JO - Macromolecular Symposia

JF - Macromolecular Symposia

SN - 1022-1360

ER -