Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior

Hiroki Ohshiro, Takeo Suga, Hiroyuki Nishide

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (Mn=10 4). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages1390
Number of pages1
Volume55
Edition1
Publication statusPublished - 2006
Event55th SPSJ Annual Meeting - Nagoya
Duration: 2006 May 242006 May 26

Other

Other55th SPSJ Annual Meeting
CityNagoya
Period06/5/2406/5/26

Fingerprint

Bearings (structural)
Polystyrenes
Polymers
Secondary batteries
Styrene
Anodes
Derivatives
Oxidation
Oxidation-Reduction

Keywords

  • Cyclic Voltammetry
  • Electrode-active Material
  • Galvinoxyl Radical
  • Radical Polymerization

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Ohshiro, H., Suga, T., & Nishide, H. (2006). Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior. In Polymer Preprints, Japan (1 ed., Vol. 55, pp. 1390)

Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior. / Ohshiro, Hiroki; Suga, Takeo; Nishide, Hiroyuki.

Polymer Preprints, Japan. Vol. 55 1. ed. 2006. p. 1390.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Ohshiro, H, Suga, T & Nishide, H 2006, Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior. in Polymer Preprints, Japan. 1 edn, vol. 55, pp. 1390, 55th SPSJ Annual Meeting, Nagoya, 06/5/24.
Ohshiro H, Suga T, Nishide H. Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior. In Polymer Preprints, Japan. 1 ed. Vol. 55. 2006. p. 1390
Ohshiro, Hiroki ; Suga, Takeo ; Nishide, Hiroyuki. / Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior. Polymer Preprints, Japan. Vol. 55 1. ed. 2006. pp. 1390
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