Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior

Hiroki Ohshiro; Takeo Suga; Hiroyuki Nishide

Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior

Hiroki Ohshiro, Takeo Suga, Hiroyuki Nishide

School of Advanced Science and Engineering

Research output: Contribution to conference › Paper › peer-review

Abstract

Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (M_n=10 ⁴). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.

Original language	English
Number of pages	1
Publication status	Published - 2006 Oct 19
Event	55th SPSJ Annual Meeting - Nagoya, Japan Duration: 2006 May 24 → 2006 May 26

Conference

Conference	55th SPSJ Annual Meeting
Country	Japan
City	Nagoya
Period	06/5/24 → 06/5/26

Keywords

Cyclic Voltammetry
Electrode-active Material
Galvinoxyl Radical
Radical Polymerization

ASJC Scopus subject areas

Engineering(all)

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title = "Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior",

abstract = "Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (Mn=10 4). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.",

keywords = "Cyclic Voltammetry, Electrode-active Material, Galvinoxyl Radical, Radical Polymerization",

author = "Hiroki Ohshiro and Takeo Suga and Hiroyuki Nishide",

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language = "English",

note = "55th SPSJ Annual Meeting ; Conference date: 24-05-2006 Through 26-05-2006",

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T1 - Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior

AU - Ohshiro, Hiroki

AU - Suga, Takeo

AU - Nishide, Hiroyuki

PY - 2006/10/19

Y1 - 2006/10/19

N2 - Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (Mn=10 4). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.

AB - Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (Mn=10 4). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.

KW - Cyclic Voltammetry

KW - Electrode-active Material

KW - Galvinoxyl Radical

KW - Radical Polymerization

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T2 - 55th SPSJ Annual Meeting

Y2 - 24 May 2006 through 26 May 2006

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