Synthesis of polystyrene bearing galvinoxyl radical and its redox behavior

Hiroki Ohshiro*, Takeo Suga, Hiroyuki Nishide

*Corresponding author for this work

Research output: Contribution to conferencePaperpeer-review

Abstract

Galvinoxyl radical, known as a stable organic radical, was selected as a new candidate for a cathodeand/or anode-active material for a secondary battery. Styrene derivative bearing the galvinoxyl radical was synthesized via four steps, and polymerized to give the precursor polymer (Mn=10 4). Chemical oxidation yielded the corresponding radical polymer. The obtained polymer was characterized by spectroscopic measurements. Electrochemical measurements revealed its stable redox behavior. The cell performance will also be reported.

Original languageEnglish
Number of pages1
Publication statusPublished - 2006 Oct 19
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: 2006 May 242006 May 26

Conference

Conference55th SPSJ Annual Meeting
Country/TerritoryJapan
CityNagoya
Period06/5/2406/5/26

Keywords

  • Cyclic Voltammetry
  • Electrode-active Material
  • Galvinoxyl Radical
  • Radical Polymerization

ASJC Scopus subject areas

  • Engineering(all)

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