Synthesis of radical polymers and their application to an organic radical battery

Takeo Suga; Kentaro Yoshimura; Hiroki Ohshiro; Hiroaki Konishi; Hiroyuki Nishide

Synthesis of radical polymers and their application to an organic radical battery

Takeo Suga^*, Kentaro Yoshimura, Hiroki Ohshiro, Hiroaki Konishi, Hiroyuki Nishide

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to conference › Paper › peer-review

2 Citations (Scopus)

Abstract

Based on the redox couples of a nitroxide radical, organic radical polymers have been utilized as the electrode-active or charge-storage component for a secondary battery, so-called "organic radical battery". Organic radical battery has several advantages: high capacity, high power-rate performance, long cycle ability, and environmentally-benign features. We report here the synthesis of a series of radical polymers and their redox properties. TEMPO-substituted polyether displayed its improved compatibility with the electrolyte solution. Photo-crosslinking of TEMPO-substituted polynorbornene was investigated as a facile and useful method leading to a slim and flexible battery. Poly (galvinoxystyrene) displayed a stable n-type redox behavior at 3.2 V vs. Li/Li⁺, which also holds considerable potential as an anode-active material, leading to purely organic-derived batteries. The cell performance will be also reported.

Original language	English
Pages	4659-4660
Number of pages	2
Publication status	Published - 2006 Dec 1
Event	55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan Duration: 2006 Sept 20 → 2006 Sept 22

Other

Other	55th Society of Polymer Science Japan Symposium on Macromolecules
Country/Territory	Japan
City	Toyama
Period	06/9/20 → 06/9/22

Keywords

Electrode-active material
Galvinoxyl radical
Nitroxide radical
Photo-crosslinking
Secondary battery

ASJC Scopus subject areas

Engineering(all)

Cite this

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title = "Synthesis of radical polymers and their application to an organic radical battery",

abstract = "Based on the redox couples of a nitroxide radical, organic radical polymers have been utilized as the electrode-active or charge-storage component for a secondary battery, so-called {"}organic radical battery{"}. Organic radical battery has several advantages: high capacity, high power-rate performance, long cycle ability, and environmentally-benign features. We report here the synthesis of a series of radical polymers and their redox properties. TEMPO-substituted polyether displayed its improved compatibility with the electrolyte solution. Photo-crosslinking of TEMPO-substituted polynorbornene was investigated as a facile and useful method leading to a slim and flexible battery. Poly (galvinoxystyrene) displayed a stable n-type redox behavior at 3.2 V vs. Li/Li+, which also holds considerable potential as an anode-active material, leading to purely organic-derived batteries. The cell performance will be also reported.",

keywords = "Electrode-active material, Galvinoxyl radical, Nitroxide radical, Photo-crosslinking, Secondary battery",

author = "Takeo Suga and Kentaro Yoshimura and Hiroki Ohshiro and Hiroaki Konishi and Hiroyuki Nishide",

year = "2006",

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note = "55th Society of Polymer Science Japan Symposium on Macromolecules ; Conference date: 20-09-2006 Through 22-09-2006",

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TY - CONF

T1 - Synthesis of radical polymers and their application to an organic radical battery

AU - Suga, Takeo

AU - Yoshimura, Kentaro

AU - Ohshiro, Hiroki

AU - Konishi, Hiroaki

AU - Nishide, Hiroyuki

PY - 2006/12/1

Y1 - 2006/12/1

N2 - Based on the redox couples of a nitroxide radical, organic radical polymers have been utilized as the electrode-active or charge-storage component for a secondary battery, so-called "organic radical battery". Organic radical battery has several advantages: high capacity, high power-rate performance, long cycle ability, and environmentally-benign features. We report here the synthesis of a series of radical polymers and their redox properties. TEMPO-substituted polyether displayed its improved compatibility with the electrolyte solution. Photo-crosslinking of TEMPO-substituted polynorbornene was investigated as a facile and useful method leading to a slim and flexible battery. Poly (galvinoxystyrene) displayed a stable n-type redox behavior at 3.2 V vs. Li/Li+, which also holds considerable potential as an anode-active material, leading to purely organic-derived batteries. The cell performance will be also reported.

AB - Based on the redox couples of a nitroxide radical, organic radical polymers have been utilized as the electrode-active or charge-storage component for a secondary battery, so-called "organic radical battery". Organic radical battery has several advantages: high capacity, high power-rate performance, long cycle ability, and environmentally-benign features. We report here the synthesis of a series of radical polymers and their redox properties. TEMPO-substituted polyether displayed its improved compatibility with the electrolyte solution. Photo-crosslinking of TEMPO-substituted polynorbornene was investigated as a facile and useful method leading to a slim and flexible battery. Poly (galvinoxystyrene) displayed a stable n-type redox behavior at 3.2 V vs. Li/Li+, which also holds considerable potential as an anode-active material, leading to purely organic-derived batteries. The cell performance will be also reported.

KW - Electrode-active material

KW - Galvinoxyl radical

KW - Nitroxide radical

KW - Photo-crosslinking

KW - Secondary battery

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M3 - Paper

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T2 - 55th Society of Polymer Science Japan Symposium on Macromolecules

Y2 - 20 September 2006 through 22 September 2006

ER -

Synthesis of radical polymers and their application to an organic radical battery

Abstract

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Keywords

ASJC Scopus subject areas

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