Synthesis of reactive functionalized oligo(p-phenylene sulfide)s

Eishun Tsuchida, Kimihisa Yamamoto, Kenichi Oyaizu, Fumiaki Suzuki, Allan S. Hay, Zhi Yuan Wang

    Research output: Contribution to journalArticle

    32 Citations (Scopus)

    Abstract

    Modification of the oligo(phenylene sulfide) chain at the ends with reactive groups such as chloro, bromo, iodo, and carboxyl to enhance its reactivity was performed. α,ω-Dihalooligo(p-phenylene sulfide) was synthesized through the oxidative polymerization of diphenyl disulfide in the presence of bis(4-halophenyl)disulfide. Linear oligo(p-phenylene sulfide) (OPS) terminated by Cl or Br with a high degree of functionality was obtained by a one-pot process. α-Carboxy-OPS was synthesized by the thermolysis of the disulfide bond of the OPS in the presence of an aromatic iodide having a carboxyl group. The carboxy-terminated OPS was used for the synthesis of polyamide-graft-OPS copolymers.

    Original languageEnglish
    Pages (from-to)409-416
    Number of pages8
    JournalMacromolecules
    Volume28
    Issue number2
    Publication statusPublished - 1995 Jan 1

    Fingerprint

    Sulfides
    Disulfides
    Thermolysis
    Graft copolymers
    Nylons
    Iodides
    Polyamides
    Polymerization

    ASJC Scopus subject areas

    • Materials Chemistry

    Cite this

    Tsuchida, E., Yamamoto, K., Oyaizu, K., Suzuki, F., Hay, A. S., & Wang, Z. Y. (1995). Synthesis of reactive functionalized oligo(p-phenylene sulfide)s. Macromolecules, 28(2), 409-416.

    Synthesis of reactive functionalized oligo(p-phenylene sulfide)s. / Tsuchida, Eishun; Yamamoto, Kimihisa; Oyaizu, Kenichi; Suzuki, Fumiaki; Hay, Allan S.; Wang, Zhi Yuan.

    In: Macromolecules, Vol. 28, No. 2, 01.01.1995, p. 409-416.

    Research output: Contribution to journalArticle

    Tsuchida, E, Yamamoto, K, Oyaizu, K, Suzuki, F, Hay, AS & Wang, ZY 1995, 'Synthesis of reactive functionalized oligo(p-phenylene sulfide)s', Macromolecules, vol. 28, no. 2, pp. 409-416.
    Tsuchida E, Yamamoto K, Oyaizu K, Suzuki F, Hay AS, Wang ZY. Synthesis of reactive functionalized oligo(p-phenylene sulfide)s. Macromolecules. 1995 Jan 1;28(2):409-416.
    Tsuchida, Eishun ; Yamamoto, Kimihisa ; Oyaizu, Kenichi ; Suzuki, Fumiaki ; Hay, Allan S. ; Wang, Zhi Yuan. / Synthesis of reactive functionalized oligo(p-phenylene sulfide)s. In: Macromolecules. 1995 ; Vol. 28, No. 2. pp. 409-416.
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    AU - Hay, Allan S.

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