Synthesis of Reactive Functionalized Oligo(p-phenylene sulfides

Eishun Tsuchida; Kimihisa Yamamoto; Kenichi Oyaizu; Fumiaki Suzuki; Allan S. Hay; Zhi Yuan Wang

doi:10.1021/ma00106a001

Synthesis of Reactive Functionalized Oligo(p-phenylene sulfides

Eishun Tsuchida^*, Kimihisa Yamamoto, Kenichi Oyaizu, Fumiaki Suzuki, Allan S. Hay, Zhi Yuan Wang

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Modification of the oligo(phenylene sulfide) chain at the ends with reactive groups such as chloro, bromo, iodo, and carboxyl to enhance its reactivtiy was performed. α, ω-Dihalooligo(p-phenylene sulfide) was synthesized through the oxidative polymerization of diphenyl disulfide in the presence of bis(4-halophenyl)disulfide. Linear oligo(p-phenylene sulfide) (OPS) terminated by Cl or Br with a high degree of functionality was obtained by a one-pot process. α-Carboxy-OPS was synthesized by the thermolysis of the disulfide bond of the OPS in the presence of an aromatic iodide having a carboxyl group. The carboxy-terminated OPS was used for the synthesis of polyamide-graft-OPS copolymers.

Original language	English
Pages (from-to)	409-416
Number of pages	8
Journal	Macromolecules
Volume	28
Issue number	2
DOIs	https://doi.org/10.1021/ma00106a001
Publication status	Published - 1995 Mar 1

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma00106a001

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abstract = "Modification of the oligo(phenylene sulfide) chain at the ends with reactive groups such as chloro, bromo, iodo, and carboxyl to enhance its reactivtiy was performed. α, ω-Dihalooligo(p-phenylene sulfide) was synthesized through the oxidative polymerization of diphenyl disulfide in the presence of bis(4-halophenyl)disulfide. Linear oligo(p-phenylene sulfide) (OPS) terminated by Cl or Br with a high degree of functionality was obtained by a one-pot process. α-Carboxy-OPS was synthesized by the thermolysis of the disulfide bond of the OPS in the presence of an aromatic iodide having a carboxyl group. The carboxy-terminated OPS was used for the synthesis of polyamide-graft-OPS copolymers.",

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T1 - Synthesis of Reactive Functionalized Oligo(p-phenylene sulfides

AU - Tsuchida, Eishun

AU - Yamamoto, Kimihisa

AU - Oyaizu, Kenichi

AU - Suzuki, Fumiaki

AU - Hay, Allan S.

AU - Wang, Zhi Yuan

PY - 1995/3/1

Y1 - 1995/3/1

N2 - Modification of the oligo(phenylene sulfide) chain at the ends with reactive groups such as chloro, bromo, iodo, and carboxyl to enhance its reactivtiy was performed. α, ω-Dihalooligo(p-phenylene sulfide) was synthesized through the oxidative polymerization of diphenyl disulfide in the presence of bis(4-halophenyl)disulfide. Linear oligo(p-phenylene sulfide) (OPS) terminated by Cl or Br with a high degree of functionality was obtained by a one-pot process. α-Carboxy-OPS was synthesized by the thermolysis of the disulfide bond of the OPS in the presence of an aromatic iodide having a carboxyl group. The carboxy-terminated OPS was used for the synthesis of polyamide-graft-OPS copolymers.

AB - Modification of the oligo(phenylene sulfide) chain at the ends with reactive groups such as chloro, bromo, iodo, and carboxyl to enhance its reactivtiy was performed. α, ω-Dihalooligo(p-phenylene sulfide) was synthesized through the oxidative polymerization of diphenyl disulfide in the presence of bis(4-halophenyl)disulfide. Linear oligo(p-phenylene sulfide) (OPS) terminated by Cl or Br with a high degree of functionality was obtained by a one-pot process. α-Carboxy-OPS was synthesized by the thermolysis of the disulfide bond of the OPS in the presence of an aromatic iodide having a carboxyl group. The carboxy-terminated OPS was used for the synthesis of polyamide-graft-OPS copolymers.

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Synthesis of Reactive Functionalized Oligo(p-phenylene sulfides

Abstract

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