Synthesis of SAPO-34 Membrane and Its Application to the Separation of Water/Acetic Acid Mixtures by Vapor Permeation

Ataher Ahmed; Sonosuke Ishiguro; Masahiro Seshimo; Bharathi Subramanian; Masahiko Matsukata

doi:10.1252/jcej.18we346

Synthesis of SAPO-34 Membrane and Its Application to the Separation of Water/Acetic Acid Mixtures by Vapor Permeation

Ataher Ahmed, Sonosuke Ishiguro, Masahiro Seshimo, Bharathi Subramanian, Masahiko Matsukata^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

CHA-type zeolite SAPO-34 membranes were synthesized on a tubular porous α-alumina support using a secondary growth method and evaluated for the separation of water/acetic acid mixtures by vapor permeation. The effects of SiO₂ molar fraction in the preparation gel on the membrane formation process and the separation properties of SAPO-34 membranes were studied. The SiO₂ molar fraction in the synthesis gel substantially influenced the separation properties of prepared membranes. The membrane synthesized using a gel with a composition of 1.0 Al₂O₃:0.9 H₃PO₄:0.6 SiO₂:0.8 TEAOH:100 H₂O demonstrated a high separation factor of 140 with water permeance of 2.2 x 10^-7 mol/m-s-Pa. Prepared SAPO-34 membranes showed resistance against acetic acid.

Original language	English
Pages (from-to)	97-104
Number of pages	8
Journal	JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Volume	55
Issue number	2
DOIs	https://doi.org/10.1252/jcej.18we346
Publication status	Published - 2022 Feb 20

Keywords

Dehydration
SAPO-34
Vapor Permeation
Water/Acetic Acid Separation
Zeolite Membrane

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

Access to Document

10.1252/jcej.18we346

Cite this

@article{0624143a8e4349398212876bd3581a2f,

title = "Synthesis of SAPO-34 Membrane and Its Application to the Separation of Water/Acetic Acid Mixtures by Vapor Permeation",

abstract = "CHA-type zeolite SAPO-34 membranes were synthesized on a tubular porous α-alumina support using a secondary growth method and evaluated for the separation of water/acetic acid mixtures by vapor permeation. The effects of SiO2 molar fraction in the preparation gel on the membrane formation process and the separation properties of SAPO-34 membranes were studied. The SiO2 molar fraction in the synthesis gel substantially influenced the separation properties of prepared membranes. The membrane synthesized using a gel with a composition of 1.0 Al2O3:0.9 H3PO4:0.6 SiO2:0.8 TEAOH:100 H2O demonstrated a high separation factor of 140 with water permeance of 2.2 x 10-7 mol/m-s-Pa. Prepared SAPO-34 membranes showed resistance against acetic acid.",

keywords = "Dehydration, SAPO-34, Vapor Permeation, Water/Acetic Acid Separation, Zeolite Membrane",

author = "Ataher Ahmed and Sonosuke Ishiguro and Masahiro Seshimo and Bharathi Subramanian and Masahiko Matsukata",

note = "Funding Information: is work was partially supported by JST CREST (Japan Science and Technology Agency, Create Revolutionary Technological Seeds for Science and Technology Innovation Program, Japan), Grant Number JPMJCR1324.",

year = "2022",

month = feb,

day = "20",

doi = "10.1252/jcej.18we346",

language = "English",

volume = "55",

pages = "97--104",

journal = "Journal of Chemical Engineering of Japan",

issn = "0021-9592",

publisher = "Society of Chemical Engineers, Japan",

number = "2",

}

TY - JOUR

T1 - Synthesis of SAPO-34 Membrane and Its Application to the Separation of Water/Acetic Acid Mixtures by Vapor Permeation

AU - Ahmed, Ataher

AU - Ishiguro, Sonosuke

AU - Seshimo, Masahiro

AU - Subramanian, Bharathi

AU - Matsukata, Masahiko

N1 - Funding Information: is work was partially supported by JST CREST (Japan Science and Technology Agency, Create Revolutionary Technological Seeds for Science and Technology Innovation Program, Japan), Grant Number JPMJCR1324.

PY - 2022/2/20

Y1 - 2022/2/20

N2 - CHA-type zeolite SAPO-34 membranes were synthesized on a tubular porous α-alumina support using a secondary growth method and evaluated for the separation of water/acetic acid mixtures by vapor permeation. The effects of SiO2 molar fraction in the preparation gel on the membrane formation process and the separation properties of SAPO-34 membranes were studied. The SiO2 molar fraction in the synthesis gel substantially influenced the separation properties of prepared membranes. The membrane synthesized using a gel with a composition of 1.0 Al2O3:0.9 H3PO4:0.6 SiO2:0.8 TEAOH:100 H2O demonstrated a high separation factor of 140 with water permeance of 2.2 x 10-7 mol/m-s-Pa. Prepared SAPO-34 membranes showed resistance against acetic acid.

AB - CHA-type zeolite SAPO-34 membranes were synthesized on a tubular porous α-alumina support using a secondary growth method and evaluated for the separation of water/acetic acid mixtures by vapor permeation. The effects of SiO2 molar fraction in the preparation gel on the membrane formation process and the separation properties of SAPO-34 membranes were studied. The SiO2 molar fraction in the synthesis gel substantially influenced the separation properties of prepared membranes. The membrane synthesized using a gel with a composition of 1.0 Al2O3:0.9 H3PO4:0.6 SiO2:0.8 TEAOH:100 H2O demonstrated a high separation factor of 140 with water permeance of 2.2 x 10-7 mol/m-s-Pa. Prepared SAPO-34 membranes showed resistance against acetic acid.

KW - Dehydration

KW - SAPO-34

KW - Vapor Permeation

KW - Water/Acetic Acid Separation

KW - Zeolite Membrane

UR - http://www.scopus.com/inward/record.url?scp=85127377045&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85127377045&partnerID=8YFLogxK

U2 - 10.1252/jcej.18we346

DO - 10.1252/jcej.18we346

M3 - Article

AN - SCOPUS:85127377045

SN - 0021-9592

VL - 55

SP - 97

EP - 104

JO - Journal of Chemical Engineering of Japan

JF - Journal of Chemical Engineering of Japan

IS - 2

ER -

Synthesis of SAPO-34 Membrane and Its Application to the Separation of Water/Acetic Acid Mixtures by Vapor Permeation

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this