Synthesis of silica gels containing imidazole groups and their binding affinity for methyl orange in water

Yukihiko Ueno, Hazime Yoshio, Manshi Ohyanagi, Koji Ikeda, Yoshiro Sekine

Research output: Contribution to journalArticle

Abstract

Silica gels containing imidazole groups or hexyl groups whose compositions are well controlled have been prepared. The imidazole group in the gel was quaternized with C4H9Br, C6H13Br or C12H25Br to obtain gels that are charged and have an alkyl chain. Their binding affinities for methyl orange in water were then investigated. We aimed to clarify the relation between the structure of the gel and its binding behaviour for small molecules in water. So the binding affinities of the unquaternized and quaternized gels were compared for methyl orange in water at various temperatures and we obtained the thermodynamic parameters for this binding. It was found that in silica gel the alkyl chain that is bound chemically to the charged site is very efficient for binding the dye in water.

Original languageEnglish
Pages (from-to)627-630
Number of pages4
JournalPolymer
Volume27
Issue number4
DOIs
Publication statusPublished - 1986

Fingerprint

Silica Gel
Silica gel
Gels
Water
Coloring Agents
Dyes
Thermodynamics
Molecules
methyl orange
imidazole
Chemical analysis
Temperature

Keywords

  • adsorption
  • affinity
  • chromatography
  • hydrophobicity
  • methyl orange
  • silica

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

Cite this

Synthesis of silica gels containing imidazole groups and their binding affinity for methyl orange in water. / Ueno, Yukihiko; Yoshio, Hazime; Ohyanagi, Manshi; Ikeda, Koji; Sekine, Yoshiro.

In: Polymer, Vol. 27, No. 4, 1986, p. 627-630.

Research output: Contribution to journalArticle

Ueno, Yukihiko ; Yoshio, Hazime ; Ohyanagi, Manshi ; Ikeda, Koji ; Sekine, Yoshiro. / Synthesis of silica gels containing imidazole groups and their binding affinity for methyl orange in water. In: Polymer. 1986 ; Vol. 27, No. 4. pp. 627-630.
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AU - Yoshio, Hazime

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AU - Ikeda, Koji

AU - Sekine, Yoshiro

PY - 1986

Y1 - 1986

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AB - Silica gels containing imidazole groups or hexyl groups whose compositions are well controlled have been prepared. The imidazole group in the gel was quaternized with C4H9Br, C6H13Br or C12H25Br to obtain gels that are charged and have an alkyl chain. Their binding affinities for methyl orange in water were then investigated. We aimed to clarify the relation between the structure of the gel and its binding behaviour for small molecules in water. So the binding affinities of the unquaternized and quaternized gels were compared for methyl orange in water at various temperatures and we obtained the thermodynamic parameters for this binding. It was found that in silica gel the alkyl chain that is bound chemically to the charged site is very efficient for binding the dye in water.

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