Synthesis of three-component C3N4/rGO/C-TiO2 photocatalyst with enhanced visible-light responsive photocatalytic deNOx activity

Chiaki Noda, Yusuke Asakura, Kyohei Shiraki, Akira Yamakata, Shu Yin

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

In order to realize high efficiency photocatalysis deNOx effect, a homogeneous three-component photocatalyst, C3N4/rGO/C-TiO2 was successfully synthesized by an in situ synthesis method. First, C3N4/rGO composite was prepared to increase the contact surface between them. Then, C-TiO2 was crystallized on the surface of the C3N4/rGO to obtain relatively dispersed C-TiO2 nanoparticles on the C3N4/rGO. The as-prepared photocatalyst was evaluated by NO removal ratio under weak visible and UV LED light irradiation. C3N4/rGO/C-TiO2 was compared with sample prepared by simple mixing of C3N4, rGO and C-TiO2 within a solution. As a result, sample prepared by in situ synthesis exhibited the highest photocatalytic activity, together with high apparent quantum efficiency. The transient absorption measurement clarified that the composite photocatalyst possessed longer carrier lifetime if compared to that of each component material, resulted to its higher photocatalytic activity. The three-component photocatalyst is thought to have shown enhancement in photocatalytic activity by Z-scheme mechanism with rGO as an electron mediator to improve the performance of Z-scheme.

Original languageEnglish
Article number124616
JournalChemical Engineering Journal
Volume390
DOIs
Publication statusPublished - 2020 Jun 15
Externally publishedYes

Keywords

  • Composite
  • Impurities in semiconductors
  • Photocatalyst
  • Solvothermal

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Fingerprint

Dive into the research topics of 'Synthesis of three-component C<sub>3</sub>N<sub>4</sub>/rGO/C-TiO<sub>2</sub> photocatalyst with enhanced visible-light responsive photocatalytic deNO<sub>x</sub> activity'. Together they form a unique fingerprint.

Cite this