Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

Tomohiro Agou, Koichi Nagata, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr 2•OEt 2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

Original languageEnglish
Pages (from-to)3806-3809
Number of pages4
JournalOrganometallics
Volume31
Issue number9
DOIs
Publication statusPublished - 2012 May 14

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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