Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent

Tomohiro Agou, Koichi Nagata, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh

    Research output: Contribution to journalArticle

    22 Citations (Scopus)

    Abstract

    The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsilyl)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr 2•OEt 2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

    Original languageEnglish
    Pages (from-to)3806-3809
    Number of pages4
    JournalOrganometallics
    Volume31
    Issue number9
    DOIs
    Publication statusPublished - 2012 May 14

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    Bearings (structural)
    Discrete Fourier transforms
    synthesis

    ASJC Scopus subject areas

    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Inorganic Chemistry

    Cite this

    Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent. / Agou, Tomohiro; Nagata, Koichi; Sakai, Heisuke; Furukawa, Yukio; Tokitoh, Norihiro.

    In: Organometallics, Vol. 31, No. 9, 14.05.2012, p. 3806-3809.

    Research output: Contribution to journalArticle

    Agou, Tomohiro ; Nagata, Koichi ; Sakai, Heisuke ; Furukawa, Yukio ; Tokitoh, Norihiro. / Synthesis, structure, and properties of a stable 1,2-dibromodialumane(4) bearing a bulky aryl substituent. In: Organometallics. 2012 ; Vol. 31, No. 9. pp. 3806-3809.
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    AU - Tokitoh, Norihiro

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