Synthesis, structures, and reactivity of kinetically stabilized anthryldiphosphene derivatives

Akihiro Tsurusaki, Noriyoshi Nagahora, Takahiro Sasamori, Kazunari Matsuda, Yoshihiko Kanemitsu, Yasuaki Watanabe, Yoshinobu Hosoi, Yukio Furukawa, Norihiro Tokitoh

    Research output: Contribution to journalArticle

    8 Citations (Scopus)

    Abstract

    The first stable anthryldiphosphenes, 1 and 2, were synthesized by utilizing kinetic stabilization of 2,4,6- tris[bis(trimethylsilyl)methyl]phenyl (Tbt) and 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl] phenyl (Bbt) groups, and were characterized by spectroscopic and X-ray crystallographic analyses. The UVvisible spectroscopic data suggested the electronic communication between the anthryl moiety and the P=P unit. It was found that TbtP=P(9- Anth) (1a: 9-Anth = 9-anthryl) showed weak fluorescence in hexane solution. Furthermore, the reactivities of anthryldiphosphene 1 with a chromium complex, chalcogenation reagents, a diene, and electron-deficient olefins have been revealed.

    Original languageEnglish
    Pages (from-to)456-478
    Number of pages23
    JournalBulletin of the Chemical Society of Japan
    Volume83
    Issue number5
    DOIs
    Publication statusPublished - 2010

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    Alkenes
    Hexanes
    Chromium
    Stabilization
    Fluorescence
    Derivatives
    X rays
    Kinetics
    Electrons
    Communication

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Tsurusaki, A., Nagahora, N., Sasamori, T., Matsuda, K., Kanemitsu, Y., Watanabe, Y., ... Tokitoh, N. (2010). Synthesis, structures, and reactivity of kinetically stabilized anthryldiphosphene derivatives. Bulletin of the Chemical Society of Japan, 83(5), 456-478. https://doi.org/10.1246/bcsj.20090295

    Synthesis, structures, and reactivity of kinetically stabilized anthryldiphosphene derivatives. / Tsurusaki, Akihiro; Nagahora, Noriyoshi; Sasamori, Takahiro; Matsuda, Kazunari; Kanemitsu, Yoshihiko; Watanabe, Yasuaki; Hosoi, Yoshinobu; Furukawa, Yukio; Tokitoh, Norihiro.

    In: Bulletin of the Chemical Society of Japan, Vol. 83, No. 5, 2010, p. 456-478.

    Research output: Contribution to journalArticle

    Tsurusaki, A, Nagahora, N, Sasamori, T, Matsuda, K, Kanemitsu, Y, Watanabe, Y, Hosoi, Y, Furukawa, Y & Tokitoh, N 2010, 'Synthesis, structures, and reactivity of kinetically stabilized anthryldiphosphene derivatives', Bulletin of the Chemical Society of Japan, vol. 83, no. 5, pp. 456-478. https://doi.org/10.1246/bcsj.20090295
    Tsurusaki, Akihiro ; Nagahora, Noriyoshi ; Sasamori, Takahiro ; Matsuda, Kazunari ; Kanemitsu, Yoshihiko ; Watanabe, Yasuaki ; Hosoi, Yoshinobu ; Furukawa, Yukio ; Tokitoh, Norihiro. / Synthesis, structures, and reactivity of kinetically stabilized anthryldiphosphene derivatives. In: Bulletin of the Chemical Society of Japan. 2010 ; Vol. 83, No. 5. pp. 456-478.
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