Synthetic studies on the seven- and eight-membered rings by the intramolecular Nozaki-Hiyama reaction of the allylic phosphates

Mitsuhiro Iwamoto, Masayuki Miyano, Masayuki Utsugi, Hatsuo Kawada, Masahisa Nakada

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    Abstract

    Synthetic studies on the seven- and eight-membered rings by the intramolecular Nozaki-Hiyama reaction of the allylic phosphates are described. The yield greatly depends on the structure of substrate; however, some complex substrates afforded desired products in high to excellent yield.

    Original languageEnglish
    Pages (from-to)8653-8657
    Number of pages5
    JournalTetrahedron Letters
    Volume45
    Issue number47
    DOIs
    Publication statusPublished - 2004 Nov 15

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    Keywords

    • Allylic phosphate
    • Carbocyclic ring
    • Intramolecular reaction
    • Nozaki-Hiyama reaction
    • Seven- and eight-membered ring

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

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