Systematic charge distribution changes in Bi- and Pb-3d transition metal perovskites

Masaki Azuma, Yuki Sakai, Takumi Nishikubo, Masaichiro Mizumaki, Tetsu Watanuki, Takashi Mizokawa, Kengo Oka, Hajime Hojo, Makoto Naka

Research output: Contribution to journalReview article

2 Citations (Scopus)

Abstract

Charge distribution changes in Bi- and Pb-3d transition metal perovskite type oxides were examined by comprehensive precise structural analysis, spectroscopy, and theoretical investigations. The change in the depth of the d level of the transition metal caused the intermetallic charge transfer. A temperature-induced charge-transfer transition in chemically modified BiNiO3 results in technologically important negative thermal expansion.

Original languageEnglish
Pages (from-to)1371-1377
Number of pages7
JournalDalton Transactions
Volume47
Issue number5
DOIs
Publication statusPublished - 2018 Jan 1

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Charge distribution
Transition metals
Charge transfer
Structural analysis
Oxides
Intermetallics
Spectroscopy
Temperature
Negative thermal expansion
perovskite

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Systematic charge distribution changes in Bi- and Pb-3d transition metal perovskites. / Azuma, Masaki; Sakai, Yuki; Nishikubo, Takumi; Mizumaki, Masaichiro; Watanuki, Tetsu; Mizokawa, Takashi; Oka, Kengo; Hojo, Hajime; Naka, Makoto.

In: Dalton Transactions, Vol. 47, No. 5, 01.01.2018, p. 1371-1377.

Research output: Contribution to journalReview article

Azuma, M, Sakai, Y, Nishikubo, T, Mizumaki, M, Watanuki, T, Mizokawa, T, Oka, K, Hojo, H & Naka, M 2018, 'Systematic charge distribution changes in Bi- and Pb-3d transition metal perovskites', Dalton Transactions, vol. 47, no. 5, pp. 1371-1377. https://doi.org/10.1039/c7dt03244g
Azuma, Masaki ; Sakai, Yuki ; Nishikubo, Takumi ; Mizumaki, Masaichiro ; Watanuki, Tetsu ; Mizokawa, Takashi ; Oka, Kengo ; Hojo, Hajime ; Naka, Makoto. / Systematic charge distribution changes in Bi- and Pb-3d transition metal perovskites. In: Dalton Transactions. 2018 ; Vol. 47, No. 5. pp. 1371-1377.
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