Abstract
We have studied a wide range of 3d transition-metal compounds by a cluster configuration-interaction analysis of the metal 2p core-level photoemission spectra. Deduced values for the charge-transfer energy Δ and the d-d Coulomb repulsion U, defined with respect to the multiplet-averaged energies, show a smooth variation as functions of cation atomic number, ligand and cation valence. Many physical properties, however, show apparently irregular variation, which we attribute to d-d exchange or multiplet effects, which also reflect upon Δeff and Ueff defined with respect to the lowest multiplet energies.
| Original language | English |
|---|---|
| Pages (from-to) | 11-15 |
| Number of pages | 5 |
| Journal | Solid State Communications |
| Volume | 83 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1992 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
Cite this
Systematics in the electronic structure of 3d transition-metal compounds. / Bocquet, A. E.; Saitoh, T.; Mizokawa, T.; Fujimori, A.
In: Solid State Communications, Vol. 83, No. 1, 1992, p. 11-15.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Systematics in the electronic structure of 3d transition-metal compounds
AU - Bocquet, A. E.
AU - Saitoh, T.
AU - Mizokawa, T.
AU - Fujimori, A.
PY - 1992
Y1 - 1992
N2 - We have studied a wide range of 3d transition-metal compounds by a cluster configuration-interaction analysis of the metal 2p core-level photoemission spectra. Deduced values for the charge-transfer energy Δ and the d-d Coulomb repulsion U, defined with respect to the multiplet-averaged energies, show a smooth variation as functions of cation atomic number, ligand and cation valence. Many physical properties, however, show apparently irregular variation, which we attribute to d-d exchange or multiplet effects, which also reflect upon Δeff and Ueff defined with respect to the lowest multiplet energies.
AB - We have studied a wide range of 3d transition-metal compounds by a cluster configuration-interaction analysis of the metal 2p core-level photoemission spectra. Deduced values for the charge-transfer energy Δ and the d-d Coulomb repulsion U, defined with respect to the multiplet-averaged energies, show a smooth variation as functions of cation atomic number, ligand and cation valence. Many physical properties, however, show apparently irregular variation, which we attribute to d-d exchange or multiplet effects, which also reflect upon Δeff and Ueff defined with respect to the lowest multiplet energies.
UR - http://www.scopus.com/inward/record.url?scp=0002707745&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0002707745&partnerID=8YFLogxK
U2 - 10.1016/0038-1098(92)90004-S
DO - 10.1016/0038-1098(92)90004-S
M3 - Article
AN - SCOPUS:0002707745
VL - 83
SP - 11
EP - 15
JO - Solid State Communications
JF - Solid State Communications
SN - 0038-1098
IS - 1
ER -