Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate

Takashi Fujihara, Tomoaki Sugaya, Akira Nagasawa, Juzo Nakayama

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The title compound, [Zn(C6H10N2S 2)4](ClO4)2, containing four inner-salt ligands, is considered to retain an inner-salt structure in the crystal structure, where the planes of the carbenium and the dithiocarboxylate moieties are nearly perpendicular to each other [85 (2)°]. The asymmetric unit consists of one-half of the complex molecule, as the complex has twofold crystallographic symmetry. The backbone C-C bond length [N2C-CS 2 = 1.488 (7) Å] is significantly shorter than that of a normal C-C single bond.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number3
DOIs
Publication statusPublished - 2004 Mar
Externally publishedYes

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Zinc
Salts
zinc
salts
Bond length
Crystal structure
Ligands
ligands
crystal structure
Molecules
symmetry
molecules
single bond
perchlorate

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate. / Fujihara, Takashi; Sugaya, Tomoaki; Nagasawa, Akira; Nakayama, Juzo.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 3, 03.2004.

Research output: Contribution to journalArticle

Fujihara, Takashi ; Sugaya, Tomoaki ; Nagasawa, Akira ; Nakayama, Juzo. / Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate. In: Acta Crystallographica Section E: Structure Reports Online. 2004 ; Vol. 60, No. 3.
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