Abstract
The title compound, [Zn(C6H10N2S 2)4](ClO4)2, containing four inner-salt ligands, is considered to retain an inner-salt structure in the crystal structure, where the planes of the carbenium and the dithiocarboxylate moieties are nearly perpendicular to each other [85 (2)°]. The asymmetric unit consists of one-half of the complex molecule, as the complex has twofold crystallographic symmetry. The backbone C-C bond length [N2C-CS 2 = 1.488 (7) Å] is significantly shorter than that of a normal C-C single bond.
| Original language | English |
|---|---|
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 60 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 2004 Mar |
| Externally published | Yes |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Structural Biology
Cite this
Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate. / Fujihara, Takashi; Sugaya, Tomoaki; Nagasawa, Akira; Nakayama, Juzo.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 3, 03.2004.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate
AU - Fujihara, Takashi
AU - Sugaya, Tomoaki
AU - Nagasawa, Akira
AU - Nakayama, Juzo
PY - 2004/3
Y1 - 2004/3
N2 - The title compound, [Zn(C6H10N2S 2)4](ClO4)2, containing four inner-salt ligands, is considered to retain an inner-salt structure in the crystal structure, where the planes of the carbenium and the dithiocarboxylate moieties are nearly perpendicular to each other [85 (2)°]. The asymmetric unit consists of one-half of the complex molecule, as the complex has twofold crystallographic symmetry. The backbone C-C bond length [N2C-CS 2 = 1.488 (7) Å] is significantly shorter than that of a normal C-C single bond.
AB - The title compound, [Zn(C6H10N2S 2)4](ClO4)2, containing four inner-salt ligands, is considered to retain an inner-salt structure in the crystal structure, where the planes of the carbenium and the dithiocarboxylate moieties are nearly perpendicular to each other [85 (2)°]. The asymmetric unit consists of one-half of the complex molecule, as the complex has twofold crystallographic symmetry. The backbone C-C bond length [N2C-CS 2 = 1.488 (7) Å] is significantly shorter than that of a normal C-C single bond.
UR - http://www.scopus.com/inward/record.url?scp=18444387406&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=18444387406&partnerID=8YFLogxK
U2 - 10.1107/S160053680400217X
DO - 10.1107/S160053680400217X
M3 - Article
VL - 60
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 3
ER -