Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate

Takashi Fujihara; Tomoaki Sugaya; Akira Nagasawa; Juzo Nakayama

doi:10.1107/S160053680400217X

Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate

Takashi Fujihara, Tomoaki Sugaya, Akira Nagasawa, Juzo Nakayama

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

The title compound, [Zn(C₆H₁₀N₂S ₂)₄](ClO₄)₂, containing four inner-salt ligands, is considered to retain an inner-salt structure in the crystal structure, where the planes of the carbenium and the dithiocarboxylate moieties are nearly perpendicular to each other [85 (2)°]. The asymmetric unit consists of one-half of the complex molecule, as the complex has twofold crystallographic symmetry. The backbone C-C bond length [N₂C-CS ₂ = 1.488 (7) Å] is significantly shorter than that of a normal C-C single bond.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	3
DOIs	https://doi.org/10.1107/S160053680400217X
Publication status	Published - 2004 Mar
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Structural Biology

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Fujihara, T., Sugaya, T., Nagasawa, A., & Nakayama, J. (2004). Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate. Acta Crystallographica Section E: Structure Reports Online, 60(3). https://doi.org/10.1107/S160053680400217X

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title = "Tetrakis(1,3-dimethylimidazolidinium-2-dithiocarboxylate-κS)zinc(II) diperchlorate",

abstract = "The title compound, [Zn(C6H10N2S 2)4](ClO4)2, containing four inner-salt ligands, is considered to retain an inner-salt structure in the crystal structure, where the planes of the carbenium and the dithiocarboxylate moieties are nearly perpendicular to each other [85 (2)°]. The asymmetric unit consists of one-half of the complex molecule, as the complex has twofold crystallographic symmetry. The backbone C-C bond length [N2C-CS 2 = 1.488 (7) {\AA}] is significantly shorter than that of a normal C-C single bond.",

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year = "2004",

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AU - Fujihara, Takashi

AU - Sugaya, Tomoaki

AU - Nagasawa, Akira

AU - Nakayama, Juzo

PY - 2004/3

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N2 - The title compound, [Zn(C6H10N2S 2)4](ClO4)2, containing four inner-salt ligands, is considered to retain an inner-salt structure in the crystal structure, where the planes of the carbenium and the dithiocarboxylate moieties are nearly perpendicular to each other [85 (2)°]. The asymmetric unit consists of one-half of the complex molecule, as the complex has twofold crystallographic symmetry. The backbone C-C bond length [N2C-CS 2 = 1.488 (7) Å] is significantly shorter than that of a normal C-C single bond.

AB - The title compound, [Zn(C6H10N2S 2)4](ClO4)2, containing four inner-salt ligands, is considered to retain an inner-salt structure in the crystal structure, where the planes of the carbenium and the dithiocarboxylate moieties are nearly perpendicular to each other [85 (2)°]. The asymmetric unit consists of one-half of the complex molecule, as the complex has twofold crystallographic symmetry. The backbone C-C bond length [N2C-CS 2 = 1.488 (7) Å] is significantly shorter than that of a normal C-C single bond.

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