The conditions of ettringite formation by the reaction of a blast furnace slag with aqueous alkaline solutions

Aya Harashima, Kimihisa Ito

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    Blast furnace (BF) slags have been utilized in cement, concrete aggregate, roadbed materials, and earth-work materials. If an appropriate control of the elution and compound formation is developed under severer environmental conditions, their usage would be more diverse. Because the chemical composition of BF slag is similar to that of Portland cement, the possibility of ettringite (3CaO·Al2O3·3CaSO4·32H2O) formation from BF slag following a mechanism similar to that of cement hydration might be possible under a wet alkaline environment. Therefore, the effect of an alkaline solution on ettringite formation from BF slags was investigated by slag-leaching experiments and thermodynamic calculations using PHREEQC. The formation of ettringite was observed only for the high pH solutions in the experiments, whereas its thermochemical possibility from the air-cooled BF slags was always expected by the calculation. The kinetic analysis showed that the dissolution of alumina from the slag may control the whole reaction rate. The mixing of granulated BF slag with air-cooled ones tended to enhance the ettringite formation. Furthermore, a technique for removing the ettringite formed in the slag was also developed.

    Original languageEnglish
    Pages (from-to)1738-1745
    Number of pages8
    JournalISIJ International
    Volume56
    Issue number10
    DOIs
    Publication statusPublished - 2016

    Fingerprint

    Slags
    Cements
    ettringite
    Concrete aggregates
    Aluminum Oxide
    Portland cement
    Air
    Hydration
    Leaching
    Reaction rates
    Dissolution
    Alumina
    Earth (planet)
    Experiments
    Thermodynamics
    Kinetics
    Chemical analysis

    Keywords

    • Alkaline solution
    • Blast furnace slag
    • Ettringite formation
    • PHREEQC
    • Reaction kinetics
    • Slag-leaching
    • Thermodynamic calculation

    ASJC Scopus subject areas

    • Mechanics of Materials
    • Mechanical Engineering
    • Metals and Alloys
    • Materials Chemistry

    Cite this

    The conditions of ettringite formation by the reaction of a blast furnace slag with aqueous alkaline solutions. / Harashima, Aya; Ito, Kimihisa.

    In: ISIJ International, Vol. 56, No. 10, 2016, p. 1738-1745.

    Research output: Contribution to journalArticle

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