The Effect of the Liquid-Crystalline Order on Releasing Dye Molecules from Liquid-Crystalline Nano-Emulsions

Shinji Bono, Masayuki Yokoyama, Yoichi Takanishi, Jun Yamamoto

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We fabricated dye-containing liquid-crystalline nano-emulsions (LCNEs) dispersed in water, and studied the controllability of releasingdye molecules from the coreof LCNEs into water. We estimated the concentration of the dye molecules held in the core of LCNEs from transmission spectrum. As a result, it was revealed that the dye molecules are released from the core of LCNEs below the characteristic release-temperature on cooling. Moreover, the depolarized static light scattering measurement was performed to estimate the Isotropic-Nematic(I-N) phase transition temperature of low molecular weight liquid crystals in the core of LCNEs. By controlling mixing ratio of binary liquid crystalline mixture, we tuned theI-N phase transition temperature. The release-temperature completely corresponds to the I-N phase transition temperature in the coreof LCNEswithin the whole mixing ratio. Thus, we confirmed that the emergence of the liquid-crystalline order in the core of LCNEs plays a principal role in releasing the dye molecules from LCNEs.

Original languageEnglish
Pages (from-to)157-162
Number of pages6
JournalMolecular Crystals and Liquid Crystals
Volume610
Issue number1
DOIs
Publication statusPublished - 2015 Mar 24
Externally publishedYes

Fingerprint

releasing
Emulsions
emulsions
Coloring Agents
Dyes
dyes
Crystalline materials
Molecules
Liquids
liquids
molecules
Superconducting transition temperature
Phase transitions
transition temperature
mixing ratios
Liquid Crystals
Water
controllability
low molecular weights
Controllability

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Science(all)

Cite this

The Effect of the Liquid-Crystalline Order on Releasing Dye Molecules from Liquid-Crystalline Nano-Emulsions. / Bono, Shinji; Yokoyama, Masayuki; Takanishi, Yoichi; Yamamoto, Jun.

In: Molecular Crystals and Liquid Crystals, Vol. 610, No. 1, 24.03.2015, p. 157-162.

Research output: Contribution to journalArticle

@article{04ff9a925c2c428290318b7b97a16af0,
title = "The Effect of the Liquid-Crystalline Order on Releasing Dye Molecules from Liquid-Crystalline Nano-Emulsions",
abstract = "We fabricated dye-containing liquid-crystalline nano-emulsions (LCNEs) dispersed in water, and studied the controllability of releasingdye molecules from the coreof LCNEs into water. We estimated the concentration of the dye molecules held in the core of LCNEs from transmission spectrum. As a result, it was revealed that the dye molecules are released from the core of LCNEs below the characteristic release-temperature on cooling. Moreover, the depolarized static light scattering measurement was performed to estimate the Isotropic-Nematic(I-N) phase transition temperature of low molecular weight liquid crystals in the core of LCNEs. By controlling mixing ratio of binary liquid crystalline mixture, we tuned theI-N phase transition temperature. The release-temperature completely corresponds to the I-N phase transition temperature in the coreof LCNEswithin the whole mixing ratio. Thus, we confirmed that the emergence of the liquid-crystalline order in the core of LCNEs plays a principal role in releasing the dye molecules from LCNEs.",
author = "Shinji Bono and Masayuki Yokoyama and Yoichi Takanishi and Jun Yamamoto",
year = "2015",
month = "3",
day = "24",
doi = "10.1080/15421406.2015.1025625",
language = "English",
volume = "610",
pages = "157--162",
journal = "Molecular Crystals and Liquid Crystals",
issn = "1542-1406",
publisher = "Taylor and Francis Ltd.",
number = "1",

}

TY - JOUR

T1 - The Effect of the Liquid-Crystalline Order on Releasing Dye Molecules from Liquid-Crystalline Nano-Emulsions

AU - Bono, Shinji

AU - Yokoyama, Masayuki

AU - Takanishi, Yoichi

AU - Yamamoto, Jun

PY - 2015/3/24

Y1 - 2015/3/24

N2 - We fabricated dye-containing liquid-crystalline nano-emulsions (LCNEs) dispersed in water, and studied the controllability of releasingdye molecules from the coreof LCNEs into water. We estimated the concentration of the dye molecules held in the core of LCNEs from transmission spectrum. As a result, it was revealed that the dye molecules are released from the core of LCNEs below the characteristic release-temperature on cooling. Moreover, the depolarized static light scattering measurement was performed to estimate the Isotropic-Nematic(I-N) phase transition temperature of low molecular weight liquid crystals in the core of LCNEs. By controlling mixing ratio of binary liquid crystalline mixture, we tuned theI-N phase transition temperature. The release-temperature completely corresponds to the I-N phase transition temperature in the coreof LCNEswithin the whole mixing ratio. Thus, we confirmed that the emergence of the liquid-crystalline order in the core of LCNEs plays a principal role in releasing the dye molecules from LCNEs.

AB - We fabricated dye-containing liquid-crystalline nano-emulsions (LCNEs) dispersed in water, and studied the controllability of releasingdye molecules from the coreof LCNEs into water. We estimated the concentration of the dye molecules held in the core of LCNEs from transmission spectrum. As a result, it was revealed that the dye molecules are released from the core of LCNEs below the characteristic release-temperature on cooling. Moreover, the depolarized static light scattering measurement was performed to estimate the Isotropic-Nematic(I-N) phase transition temperature of low molecular weight liquid crystals in the core of LCNEs. By controlling mixing ratio of binary liquid crystalline mixture, we tuned theI-N phase transition temperature. The release-temperature completely corresponds to the I-N phase transition temperature in the coreof LCNEswithin the whole mixing ratio. Thus, we confirmed that the emergence of the liquid-crystalline order in the core of LCNEs plays a principal role in releasing the dye molecules from LCNEs.

UR - http://www.scopus.com/inward/record.url?scp=84936802698&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84936802698&partnerID=8YFLogxK

U2 - 10.1080/15421406.2015.1025625

DO - 10.1080/15421406.2015.1025625

M3 - Article

AN - SCOPUS:84936802698

VL - 610

SP - 157

EP - 162

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

SN - 1542-1406

IS - 1

ER -