The effect of Zr substitution on saturation magnetization in (Sm1-xZrx)(Fe0.8Co0.2)12 compound with the ThMn12 structure

P. Tozman, Y. K. Takahashi*, H. Sepehri-Amin, D. Ogawa, S. Hirosawa, K. Hono

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Zr is one of the essential elements to stabilize the ThMn12 structure in rare earth (R) transition metal (M) hard magnetic compounds, RM12. In this work, the effects of Zr on the intrinsic hard magnetic properties of (Sm1-x Zrx)(Fe0.8Co0.2)12 compounds are investigated using epitaxially grown thin films. The increase of Zr substitution for Sm from x = 0 to 0.26 for (Sm1-x Zrx)(Fe0.8Co0.2)12 increases saturation magnetization (μ0Ms) from 1.78 T to 1.90 T, the highest value reported for hard magnetic compounds. The largest μ0Ha and Tc for Zr-doped samples were found to be 9.8 T and 671 K for x = 0.18 which is superior to those for Nd2Fe14B. Sm-rich Sm1.30Zr0.27(Fe0.8Co0.2)12, obtained as sub-μm thick films, has remanence, μ0Mr of 1 T, which appears to be useful for near-field applications such as micro-electro-machines and magnetic recording media if microstructure can be optimized to obtain a sufficient coercivity.

Original languageEnglish
Pages (from-to)114-121
Number of pages8
JournalActa Materialia
Volume178
DOIs
Publication statusPublished - 2019 Oct 1
Externally publishedYes

Keywords

  • Coercivity
  • Magnetic properties
  • Magnetization
  • Permanent magnet
  • ThMn structure

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

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