The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals

Kenichi Oyaizu; Eishun Tsuchida

doi:10.1021/ja021374q

The first oxovanadium ring in [{O=V(salen)}₂(μ-F)][VO(salen)][BF₄] ·(CH₂Cl₂)_x crystals

Kenichi Oyaizu, Eishun Tsuchida^*

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The crystal structure of [{OV^V(salen)}₂(μ-F)][V^IVO(salen)][BF₄]·(CH₂Cl₂)_x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH₂Cl₂ molecules.

Original language	English
Pages (from-to)	5630-5631
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	19
DOIs	https://doi.org/10.1021/ja021374q
Publication status	Published - 2003 May 14

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja021374q

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abstract = "The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 {\AA} that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.",

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PY - 2003/5/14

Y1 - 2003/5/14

N2 - The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.

AB - The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.

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The first oxovanadium ring in [{O=V(salen)}₂(μ-F)][VO(salen)][BF₄] ·(CH₂Cl₂)_x crystals

Abstract

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