The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals

Kenichi Oyaizu, Eishun Tsuchida

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.

Original languageEnglish
Pages (from-to)5630-5631
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number19
DOIs
Publication statusPublished - 2003 May 14

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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