The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals

Kenichi Oyaizu, Eishun Tsuchida

    Research output: Contribution to journalArticle

    17 Citations (Scopus)

    Abstract

    The crystal structure of [{OVV(salen)}2(μ-F)][VIVO(salen)][BF4]·(CH2Cl2)x revealed a hollow cavity with a diameter of 5.3 Å that penetrates through the crystal, and a remarkable cyclic chain of the [VO(salen)] unit, a motif that has never been fashioned from oxometal building blocks. These features endow the crystal with a molecular sievelike property for the rapid, reversible, and size-selective absorption of guest CH2Cl2 molecules.

    Original languageEnglish
    Pages (from-to)5630-5631
    Number of pages2
    JournalJournal of the American Chemical Society
    Volume125
    Issue number19
    DOIs
    Publication statusPublished - 2003 May 14

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    Crystals
    Crystal structure
    Molecules
    disalicylaldehyde ethylenediamine

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    The first oxovanadium ring in [{O=V(salen)}2(μ-F)][VO(salen)][BF4] ·(CH2Cl2)x crystals. / Oyaizu, Kenichi; Tsuchida, Eishun.

    In: Journal of the American Chemical Society, Vol. 125, No. 19, 14.05.2003, p. 5630-5631.

    Research output: Contribution to journalArticle

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