The grand partition function of dilute biregular solutions

Meguru Nagamori, Kimihisa Ito, Motonori Tokuda

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

It has been demonstrated that the grand partition function (GPF) of biregular solutions contains in one single equation such thermodynamic principles as Henry's law, Raoult's law, the Gibbs-Duhem relation, Raoultian activity coefficients and their finite power series, Wagner's rec-iprocity, Schenck-Frohberg-Steinmetz's interchange, Lupis-Elliott's additivity, Mori-Morooka's disparity, and Darken's quadratic formalism. The logarithm of the Raoultian activity coefficient of species i, In γi should not be expressed by the Taylor series expansion, lest its truncation infringe the Gibbs-Duhem equation. The GPF methodology establishes that In γi, is not a vector but a scalar point function, free from any path dependence. While Darken's quadratic formalism employs three parameters to describe a ternary solution, the present biregularity approximation offers an alternative using seven empirical parameters, in case better accuracy is needed.

Original languageEnglish
Pages (from-to)703-711
Number of pages9
JournalMetallurgical and Materials Transactions B
Volume25
Issue number5
DOIs
Publication statusPublished - 1994 Oct

ASJC Scopus subject areas

  • Engineering(all)

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