The impact of air pollutants on rainwater chemistry during “urban-induced heavy rainfall” in downtown Tokyo, Japan

Ryunosuke Uchiyama, Hiroshi Okochi, Naoya Katsumi, Hiroko Ogata

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    5 Citations (Scopus)

    Abstract

    In order to clarify the impact of air pollution on the formation of sudden and locally distributed heavy rain in urban areas (hereafter UHR = urban-induced heavy rain), we analyzed inorganic ions in rainwater samples collected on an event basis over 5 years from October 2012 to December 2016 in Shinjuku, Tokyo. Hourly rainfall amounts and wet deposition fluxes of acidic components (the sum of H+, NH4 +, NO3 , and nonsea-salt SO4 2−) in UHR were 13.1 and 17.8 times larger than those in normal rainfall, respectively, indicating that large amount of air pollutants were scavenged and deposited by UHR with large amounts of rainfall. The level of air pollutants, such as NO2, SO2, and potential ozone, in the ambient air increased just before the formation of UHR and decreased sharply at the end of the UHR event. These results indicate that NO2, which was formed secondarily by oxidants, was further oxidized by HO radicals and formed HNO3 just before the formation of UHR, which was subsequently scavenged by UHR.

    Original languageEnglish
    Pages (from-to)6502-6519
    Number of pages18
    JournalJournal of Geophysical Research: Atmospheres
    Volume122
    Issue number12
    DOIs
    Publication statusPublished - 2017 Jun 27

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    Keywords

    • acidic
    • aerosol
    • heat island
    • heavy rain
    • oxidation
    • urban

    ASJC Scopus subject areas

    • Geophysics
    • Oceanography
    • Forestry
    • Ecology
    • Aquatic Science
    • Water Science and Technology
    • Soil Science
    • Geochemistry and Petrology
    • Earth-Surface Processes
    • Atmospheric Science
    • Earth and Planetary Sciences (miscellaneous)
    • Space and Planetary Science
    • Palaeontology

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