The inclusion of charge transfer to the conduction band in a cluster model analysis of core level line shapes

A. E. Bocquet, Takashi Mizokawa, K. Mamiya, A. Fujimori, M. Matoba, S. Anzait, S. Suga

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

We have extended the single-impurity cluster model to include the effects of charge transfer to the conduction band for the interpretation of the core level photoemission spectra of highly correlated, small-gap semiconducting and metallic transition metal compounds. The model includes the charge fluctuations between the local transition metal site and the conduction band and has been successfully applied to reinterpret the spectra of some 3d transition metal chalcogenides, reproducing well the large asymmetry of the main peaks, as well as the other satellite structures.

Original languageEnglish
Article number001
JournalJournal of Physics: Condensed Matter
Volume7
Issue number31
DOIs
Publication statusPublished - 1995
Externally publishedYes

Fingerprint

Core levels
Conduction bands
Transition metals
line shape
Charge transfer
conduction bands
transition metals
charge transfer
Transition metal compounds
inclusions
Chalcogenides
Photoemission
metal compounds
chalcogenides
Impurities
photoelectric emission
asymmetry
impurities

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials

Cite this

The inclusion of charge transfer to the conduction band in a cluster model analysis of core level line shapes. / Bocquet, A. E.; Mizokawa, Takashi; Mamiya, K.; Fujimori, A.; Matoba, M.; Anzait, S.; Suga, S.

In: Journal of Physics: Condensed Matter, Vol. 7, No. 31, 001, 1995.

Research output: Contribution to journalArticle

Bocquet, A. E. ; Mizokawa, Takashi ; Mamiya, K. ; Fujimori, A. ; Matoba, M. ; Anzait, S. ; Suga, S. / The inclusion of charge transfer to the conduction band in a cluster model analysis of core level line shapes. In: Journal of Physics: Condensed Matter. 1995 ; Vol. 7, No. 31.
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AU - Suga, S.

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