The investigation of Ti-modified LiCoO2 materials for lithium ion battery

Jinpeng Yu, Zenghui Han, Xiaohong Hu, Hui Zhan, Yunhong Zhou, Xingjiang Liu

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

EDAX measurement reveals that the atomic ratio of Ti/(Ti + Co) is much higher than the mole feed ratios in the preparation for the LiCo 0.99Ti0.01O2 material. XPS observation further tells that in LiCo0.998Ti0.002O2 phase with quite low Ti amount, almost no Ti can enter into the LiCoO2 lattice, it is more inclined to enrich in the particle surface. Electrochemical examinations show that the cycling stability of LiCo0.998Ti 0.002O2 is as good as that of LiCoO2/LiCo 0.99Ti0.01O2 composite between 3.0 and 4.3 V, and the latter has a better rate performance. It is considered that the difference of the high rate performance between the Ti-modified LiCoO 2 materials is more likely to originate from the different particle characteristics, when their Ti amounts are low enough.

Original languageEnglish
Pages (from-to)136-139
Number of pages4
JournalJournal of Power Sources
Volume262
DOIs
Publication statusPublished - 2014 Sep 15

Fingerprint

electric batteries
lithium
Energy dispersive spectroscopy
ions
X ray photoelectron spectroscopy
examination
preparation
cycles
composite materials
Composite materials
Lithium-ion batteries

Keywords

  • Core-shell structure
  • Doping
  • Lithium batteries
  • Rate performance

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Energy Engineering and Power Technology
  • Renewable Energy, Sustainability and the Environment
  • Physical and Theoretical Chemistry

Cite this

The investigation of Ti-modified LiCoO2 materials for lithium ion battery. / Yu, Jinpeng; Han, Zenghui; Hu, Xiaohong; Zhan, Hui; Zhou, Yunhong; Liu, Xingjiang.

In: Journal of Power Sources, Vol. 262, 15.09.2014, p. 136-139.

Research output: Contribution to journalArticle

Yu, Jinpeng ; Han, Zenghui ; Hu, Xiaohong ; Zhan, Hui ; Zhou, Yunhong ; Liu, Xingjiang. / The investigation of Ti-modified LiCoO2 materials for lithium ion battery. In: Journal of Power Sources. 2014 ; Vol. 262. pp. 136-139.
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AB - EDAX measurement reveals that the atomic ratio of Ti/(Ti + Co) is much higher than the mole feed ratios in the preparation for the LiCo 0.99Ti0.01O2 material. XPS observation further tells that in LiCo0.998Ti0.002O2 phase with quite low Ti amount, almost no Ti can enter into the LiCoO2 lattice, it is more inclined to enrich in the particle surface. Electrochemical examinations show that the cycling stability of LiCo0.998Ti 0.002O2 is as good as that of LiCoO2/LiCo 0.99Ti0.01O2 composite between 3.0 and 4.3 V, and the latter has a better rate performance. It is considered that the difference of the high rate performance between the Ti-modified LiCoO 2 materials is more likely to originate from the different particle characteristics, when their Ti amounts are low enough.

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