Abstract
The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O4 at 63.4°C is +19 cm3 mol-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.
Original language | English |
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Pages (from-to) | 2168-2170 |
Number of pages | 3 |
Journal | Canadian Journal of Chemistry |
Volume | 64 |
Issue number | 11 |
Publication status | Published - 1986 |
Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
- Organic Chemistry
- Catalysis
Cite this
The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution. / Ishihara, Koji; Swaddle, Thomas Wilson.
In: Canadian Journal of Chemistry, Vol. 64, No. 11, 1986, p. 2168-2170.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The pressure dependence of rates of homolytic fission of metal-ligand bonds in aqueous solution
AU - Ishihara, Koji
AU - Swaddle, Thomas Wilson
PY - 1986
Y1 - 1986
N2 - The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O4 at 63.4°C is +19 cm3 mol-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.
AB - The volume of activation for the exclusively homolytic decomposition of protonated 4-pyridylmethylchromium(III) ion in aqueous HC1O4 at 63.4°C is +19 cm3 mol-1, with negligible dependence on pressure up to 350 MPa at least. The origins of the strongly positive volumes of activation that characterize homolysis of complex cations in aqueous solution are examined.
UR - http://www.scopus.com/inward/record.url?scp=1542619590&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=1542619590&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:1542619590
VL - 64
SP - 2168
EP - 2170
JO - Canadian Journal of Chemistry
JF - Canadian Journal of Chemistry
SN - 0008-4042
IS - 11
ER -