The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes

Takanori Shibata; Kyoko Takami; Yoshikazu Arai; Kyoji Tsachikaina; Shunsuke Maekawa

doi:10.1246/bcsj.77.1937

The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes

Takanori Shibata, Kyoko Takami, Yoshikazu Arai, Kyoji Tsachikaina, Shunsuke Maekawa

School of Advanced Science and Engineering

Research output: Contribution to journal › Article

Abstract

Lithium butatrienolates were prepared in situ by the 1,4-elimination from 2-butynyl trimethylsilyl ethers along with a retro-Brook rearrangement. The addition reaction of the enolates with the aldehydes afforded β-hydroxy-α-vinyl-idene acylsilanes.

Original language	English
Pages (from-to)	1937-1938
Number of pages	2
Journal	Bulletin of the Chemical Society of Japan
Volume	77
Issue number	10
DOIs	https://doi.org/10.1246/bcsj.77.1937
Publication status	Published - 2004 Oct 1

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/bcsj.77.1937

Fingerprint Dive into the research topics of 'The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes'. Together they form a unique fingerprint.

Cite this

Shibata, T., Takami, K., Arai, Y., Tsachikaina, K., & Maekawa, S. (2004). The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes. Bulletin of the Chemical Society of Japan, 77(10), 1937-1938. https://doi.org/10.1246/bcsj.77.1937

@article{d4ec4f578b1641ebb7e0723b45b69da9,

title = "The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes",

abstract = "Lithium butatrienolates were prepared in situ by the 1,4-elimination from 2-butynyl trimethylsilyl ethers along with a retro-Brook rearrangement. The addition reaction of the enolates with the aldehydes afforded β-hydroxy-α-vinyl-idene acylsilanes.",

author = "Takanori Shibata and Kyoko Takami and Yoshikazu Arai and Kyoji Tsachikaina and Shunsuke Maekawa",

year = "2004",

month = oct,

day = "1",

doi = "10.1246/bcsj.77.1937",

language = "English",

volume = "77",

pages = "1937--1938",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Chemical Society of Japan",

number = "10",

}

TY - JOUR

T1 - The reaction of butatrienolates with aldehydes for the syntheses of α-vinylidene acylsilanes

AU - Shibata, Takanori

AU - Takami, Kyoko

AU - Arai, Yoshikazu

AU - Tsachikaina, Kyoji

AU - Maekawa, Shunsuke

PY - 2004/10/1

Y1 - 2004/10/1

N2 - Lithium butatrienolates were prepared in situ by the 1,4-elimination from 2-butynyl trimethylsilyl ethers along with a retro-Brook rearrangement. The addition reaction of the enolates with the aldehydes afforded β-hydroxy-α-vinyl-idene acylsilanes.

AB - Lithium butatrienolates were prepared in situ by the 1,4-elimination from 2-butynyl trimethylsilyl ethers along with a retro-Brook rearrangement. The addition reaction of the enolates with the aldehydes afforded β-hydroxy-α-vinyl-idene acylsilanes.

UR - http://www.scopus.com/inward/record.url?scp=8444247178&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=8444247178&partnerID=8YFLogxK

U2 - 10.1246/bcsj.77.1937

DO - 10.1246/bcsj.77.1937

M3 - Article

AN - SCOPUS:8444247178

VL - 77

SP - 1937

EP - 1938

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

SN - 0009-2673

IS - 10

ER -