The relationship between the manganese(II) zero-field interaction and Mn(II)/Mn(III) redox potential of Mn(4′-X-terpy)2 complexes

Jessica Gätjens, Martin Sjödin, Vincent L. Pecoraro, Sun Un

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The Mn(II)/Mn(III) redox potentials and Mn(II) zero-field interactions were measured for a series of Mn(II)(4′-X-terpy)2 complexes as a function of the electron-donating properties of the 4′-substituent. The two properties were found to be linearly related to each other. Density functional calculations demonstrated that the variation of both the redox potential and zero-field interaction depended on the charge on the center nitrogen of the terpy ligand that was modulated by the 4′-substituent. A similar relationship was found for Mn(II) complexes formed with the N,N-bis(2-ethyl-5-methylimidazol-4-ylmethyl)aminopropane ligand, indicating that the relationship between the Mn(II) zero-field interaction and the Mn(II)/Mn(III) redox potential was likely to be general.

Original languageEnglish
Pages (from-to)13825-13827
Number of pages3
JournalJournal of the American Chemical Society
Volume129
Issue number45
DOIs
Publication statusPublished - 2007 Nov 14
Externally publishedYes

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Manganese
Oxidation-Reduction
4-methylimidazole
Ligands
Density functional theory
Nitrogen
Electrons

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

The relationship between the manganese(II) zero-field interaction and Mn(II)/Mn(III) redox potential of Mn(4′-X-terpy)2 complexes. / Gätjens, Jessica; Sjödin, Martin; Pecoraro, Vincent L.; Un, Sun.

In: Journal of the American Chemical Society, Vol. 129, No. 45, 14.11.2007, p. 13825-13827.

Research output: Contribution to journalArticle

Gätjens, Jessica ; Sjödin, Martin ; Pecoraro, Vincent L. ; Un, Sun. / The relationship between the manganese(II) zero-field interaction and Mn(II)/Mn(III) redox potential of Mn(4′-X-terpy)2 complexes. In: Journal of the American Chemical Society. 2007 ; Vol. 129, No. 45. pp. 13825-13827.
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