The structure of H2SO4 monolayers on Au (111)

M. S. Zei, Daniel Alberto Scherson, G. Lehmpfuhl, D. M. Kolb

Research output: Contribution to journal › Article

44 Citations (Scopus)

Abstract

Au (111) electrodes have been emersed from sulphuric acid solutions and their surfaces studied in UHV by LEED, RHEED and AES. It is shown that, after evacuation, sulphuric acid forms an ordered two-dimensional overlayer on Au (111), the structure of which bears some relation to that of crystalline H2SO4. This H2SO4 overlayer, which is independent of the emersion potential, does not remove the (1 × 23) surface reconstruction of Au (111).

Original languageEnglish
Pages (from-to)99-105
Number of pages7
JournalJournal of Electroanalytical Chemistry
Volume229
Issue number1-2
DOIs
Publication statusPublished - 1987 Aug 10
Externally publishedYes

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Monolayers
Reflection high energy electron diffraction
Acids
Surface reconstruction
Crystalline materials
Electrodes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemical Engineering(all)
  • Electrochemistry

Cite this

Zei, M. S., Scherson, D. A., Lehmpfuhl, G., & Kolb, D. M. (1987). The structure of H2SO4 monolayers on Au (111). Journal of Electroanalytical Chemistry, 229(1-2), 99-105. https://doi.org/10.1016/0022-0728(87)85133-1

The structure of H2SO4 monolayers on Au (111). / Zei, M. S.; Scherson, Daniel Alberto; Lehmpfuhl, G.; Kolb, D. M.

In: Journal of Electroanalytical Chemistry, Vol. 229, No. 1-2, 10.08.1987, p. 99-105.

Research output: Contribution to journal › Article

Zei, MS, Scherson, DA, Lehmpfuhl, G & Kolb, DM 1987, 'The structure of H2SO4 monolayers on Au (111)', Journal of Electroanalytical Chemistry, vol. 229, no. 1-2, pp. 99-105. https://doi.org/10.1016/0022-0728(87)85133-1
Zei MS, Scherson DA, Lehmpfuhl G, Kolb DM. The structure of H2SO4 monolayers on Au (111). Journal of Electroanalytical Chemistry. 1987 Aug 10;229(1-2):99-105. https://doi.org/10.1016/0022-0728(87)85133-1
Zei, M. S. ; Scherson, Daniel Alberto ; Lehmpfuhl, G. ; Kolb, D. M. / The structure of H2SO4 monolayers on Au (111). In: Journal of Electroanalytical Chemistry. 1987 ; Vol. 229, No. 1-2. pp. 99-105.
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