The syntheses of transparent thin layers and spherical particles of nanoporous silicas

Ryouya Hashimoto, Megumi Sato, Naoki Shimura, Andre Ayral, Makoto Ogawa

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Thin layers of silica-surfactant hybrids with the thickness of several tens of nm formed on flat substrate from basic aqueous methanol solution containing tetraethoxysilane, behenyltrimethylammonium chloride, and ammonia. From the same solution, micrometer sized spherical particles of silica-surfactant hybrids were obtained. Both film and spherical particles were transformed to nanoporous silicas by calcination in air. The synthetic variables have been examined to find following dominant experimental parameters; the pore size of nanoporous silica spherical particles can be controlled by the synthetic temperature and the thickness of the films was varied by the amount of base.

Original languageEnglish
Pages (from-to)867-871
Number of pages5
JournalNippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
Volume119
Issue number1395
Publication statusPublished - 2011 Nov

Fingerprint

Silicon Dioxide
Silica
silicon dioxide
synthesis
Surface-Active Agents
Surface active agents
surfactants
Ammonia
Calcination
roasting
Pore size
Methanol
micrometers
Chlorides
ammonia
methyl alcohol
chlorides
porosity
air
Polymers

Keywords

  • Deposition
  • Nanoporous silica
  • Spherical particle
  • Transparent film

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry
  • Chemistry(all)
  • Condensed Matter Physics

Cite this

The syntheses of transparent thin layers and spherical particles of nanoporous silicas. / Hashimoto, Ryouya; Sato, Megumi; Shimura, Naoki; Ayral, Andre; Ogawa, Makoto.

In: Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan, Vol. 119, No. 1395, 11.2011, p. 867-871.

Research output: Contribution to journalArticle

Hashimoto, Ryouya ; Sato, Megumi ; Shimura, Naoki ; Ayral, Andre ; Ogawa, Makoto. / The syntheses of transparent thin layers and spherical particles of nanoporous silicas. In: Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan. 2011 ; Vol. 119, No. 1395. pp. 867-871.
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