Thermal behaviour of the precursors of ruthenia-titania based mixed oxides

N. K. Labhsetwar, V. Balek, S. Rayalu, T. Terasaka, A. Yamazaki, J. Šubrt, H. Haneda, T. Mitsuhashi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Studies on ruthenia-titania based materials have been attractive because of their catalytic properties as well as due to the possibility of solid solution formation. Samples of pure ruthenia and ruthenia containing various amounts of titania (10-70 mol%) were investigated during heating of their hydroxide precursors from 20 to 800°C in air using emanation thermal analysis (ETA), thermogravimetry (TG), and differential thermal analysis (DTA). The resulting mixed oxide type materials were characterized by X-ray diffraction (XRD), which indicate the presence of three ruthenia-titania phases. The onset temperature of the crystallization of materials was identified by ETA results, whereas DTA effects characterized the crystallization in bulk of the samples. A good agreement was found between the ETA results and other characterization techniques used. ETA results, indicating the microstructural changes in surface and subsurface of ruthenia-titania based catalytic materials, can be used for optimization of their synthesis protocols to achieve the better physical properties.

Original languageEnglish
Pages (from-to)671-677
Number of pages7
JournalJournal of Thermal Analysis and Calorimetry
Volume80
Issue number3
DOIs
Publication statusPublished - 2005 Jun 1

Keywords

  • DTA
  • Emanation thermal analysis
  • Ruthenia
  • Ruthenia-titania
  • Solid solution
  • Thermogravimetry

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Thermal behaviour of the precursors of ruthenia-titania based mixed oxides'. Together they form a unique fingerprint.

  • Cite this

    Labhsetwar, N. K., Balek, V., Rayalu, S., Terasaka, T., Yamazaki, A., Šubrt, J., Haneda, H., & Mitsuhashi, T. (2005). Thermal behaviour of the precursors of ruthenia-titania based mixed oxides. Journal of Thermal Analysis and Calorimetry, 80(3), 671-677. https://doi.org/10.1007/s10973-005-0712-8