Thermochemical properties of some liquid III-V alloys

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Abstract

Heat contents of the Ga-P, In-P, Ga-As and In-As systems were measured by a drop-calorimeter in the respective concentration ranges of Xp = 0.02 to 0.1, Xp = 0.05 to 0.5, XAs = 0.05 to 0.5 and XAs = 0.05 to 0.5, and 1n the temperature ranges of 800 to 1550K. The enthalpies of fusion for InP, GaAs and InAs were determined as 44.09 ± 0.09, 53.36 ± 0.10 and 37.92 ± 0.14kJ g-atom-, respectively, at the corresponding melting points of 1340 ± 1, 1514 ± 1 and 1221 ± 1K. A thermodynamic analysis method was applied to calculate thermodynamic quantities such as the Gibbs free energies of mixing in the liquid Ga-P, In-P, Ga-As and In-As systems. An optimization of experimental data for these systems were carried out, and the coefficients for the excess Gibbs free energies of mixing for the liquid phase were derived in this study.

Original languageEnglish
Pages (from-to)287-294
Number of pages8
JournalThermochimica Acta
Volume163
Issue numberC
DOIs
Publication statusPublished - 1990 Jun 29
Externally publishedYes

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thermochemical properties
Gibbs free energy
Enthalpy
drop calorimeters
enthalpy
Thermodynamics
thermodynamics
Liquids
liquids
Calorimeters
melting points
Melting point
liquid phases
Fusion reactions
fusion
Atoms
optimization
coefficients
atoms
Temperature

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Physical and Theoretical Chemistry

Cite this

Thermochemical properties of some liquid III-V alloys. / Yamaguchi, Katsunori; Itagaki, K.

In: Thermochimica Acta, Vol. 163, No. C, 29.06.1990, p. 287-294.

Research output: Contribution to journalArticle

Yamaguchi, Katsunori ; Itagaki, K. / Thermochemical properties of some liquid III-V alloys. In: Thermochimica Acta. 1990 ; Vol. 163, No. C. pp. 287-294.
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