Thermodynamic investigation of the effect of oxygen and hydrogen chloride potential upon generation and decomposition behavior of dioxins

Nagahiro Saito, Takahiro Ishizaki, Akio Fuwa

    Research output: Contribution to journalArticle

    3 Citations (Scopus)

    Abstract

    The thermodynamic equilibrium of the C-H-O-Cl system has been calculated to elucidate the generation and decomposition behavior of dioxins, and is discussed from the viewpoint of the oxygen and hydrogen chloride potential. The dioxins behavior is greatly dependent on the oxygen potential, i.e. higher temperature and oxygen potential lead to the complete decomposition of dioxins, while low hydrogen chloride potential under insufficient oxygen condition leads to an increase of multi-chlorine displacement of dioxins.

    Original languageEnglish
    Pages (from-to)161-179
    Number of pages19
    JournalToxicological and Environmental Chemistry
    Volume75
    Issue number3-4
    Publication statusPublished - 2000

    Keywords

    • C-H-O-Cl system
    • Dioxins
    • Hydrogen chloride potential
    • Oxygen potential
    • Thermodynamic equilibrium

    ASJC Scopus subject areas

    • Environmental Science(all)
    • Environmental Chemistry
    • Health, Toxicology and Mutagenesis
    • Toxicology

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