Thermodynamics of FetO-TiO2-SiO2 melts in equilibrium with solid iron

Kenji Matsuzaki, Kimihisa Ito

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The activities of FetO in a FetO-TiO2-SiO2 system in equilibrium with solid iron at 1 623 and 1 673 K were measured by equilibrating molten slag with a H2-CO2 gas mixture. The iso-activity contour of FetO for this system was calculated and influence of slag composition on the activity coefficient of FetO and the Fe3+/Fe2+ ratio was determined. On the assumption that the FetO-TiO2-SiO2 system is based on an ideal mixture of the pseudo-binary components, the activities of SiO2 and TiO2 were estimated using Richardson's method.

Original languageEnglish
Pages (from-to)562-565
Number of pages4
JournalISIJ International
Volume37
Issue number6
DOIs
Publication statusPublished - 1997 Jan 1

Keywords

  • Activity of FeO
  • Fe/Fe ratio
  • FeO-TiO-SiO system
  • Richardson's method

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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