Time-dependent density functional theory (TDDFT) calculations for core-excited states: Assessment of an exchange functional combining the Becke88 and van Leeuwen-Baerends-type functionals

Yutaka Imamura; Hiromi Nakai

doi:10.1016/j.cplett.2005.11.084

Time-dependent density functional theory (TDDFT) calculations for core-excited states: Assessment of an exchange functional combining the Becke88 and van Leeuwen-Baerends-type functionals

Yutaka Imamura, Hiromi Nakai

School of Advanced Science and Engineering

Research output: Contribution to journal › Article

30 Citations (Scopus)

Abstract

We propose and assess an exchange-correlation functional, BmLBLYP, in order to describe both core and valence excited states with high accuracy in the time-dependent density functional theory (TDDFT) calculations. The BmLBLYP functional is designed to adopt the modified van Leeuwen-Baerends (mLB) and the Becke 88 (B88) exchange functionals, combined with the Lee-Yang-Parr (LYP) correlation functional. The combination of BmLBLYP is based on the analysis that the LB94 functional behaves better for the core excitations than the B88 functional, while the opposite is true for the valence excitations. Numerical assessment confirms the high accuracy and wide applicability of the BmLBLYP functional.

Original language	English
Pages (from-to)	297-303
Number of pages	7
Journal	Chemical Physics Letters
Volume	419
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2005.11.084
Publication status	Published - 2006 Feb 15

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ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Cite this

Imamura, Y., & Nakai, H. (2006). Time-dependent density functional theory (TDDFT) calculations for core-excited states: Assessment of an exchange functional combining the Becke88 and van Leeuwen-Baerends-type functionals. Chemical Physics Letters, 419(1-3), 297-303. https://doi.org/10.1016/j.cplett.2005.11.084

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10.1016/j.cplett.2005.11.084