Topotactic conversion of layered silicate RUB-15 to silica sodalite through interlayer condensation in N-methylformamide

Masakazu Koike, Yusuke Asakura, Megumi Sugihara, Yoshiyuki Kuroda, Hidehiro Tsuzura, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    Silica sodalite was obtained using topotactic conversion of layered silicate RUB-15 through stepwise processes that consisted of the control of stacking sequence of the layers, interlayer condensation by refluxing, and elimination of intercalated guest species. The interlayer condensation of RUB-15, in which acetic acid was pre-intercalated between the layers to control the stacking sequence, afforded a sodalite framework containing organic guest species by refluxing in N-methylformamide (NMF). The pre-intercalated acetic acid molecules were largely replaced with NMF. This formation process of silica sodalite containing large amounts of intercalated organic guest species is in clear contrast to the previously reported process that used direct calcination of an intercalation compound of layered RUB-15 accommodating acetic acid between the layers. Calcination of the condensed product provided sodalite with fewer defects than the directly calcined product, thus indicating the advantage of the stepwise process. The method reported here is useful for the preparation of pure silica sodalite with relatively low defects and plate-like morphology.

    Original languageEnglish
    Pages (from-to)10232-10239
    Number of pages8
    JournalDalton Transactions
    Volume46
    Issue number31
    DOIs
    Publication statusPublished - 2017

    Fingerprint

    methylformamide
    Silicates
    Silicon Dioxide
    Acetic Acid
    Condensation
    Calcination
    Intercalation compounds
    Defects
    Molecules

    ASJC Scopus subject areas

    • Inorganic Chemistry

    Cite this

    Topotactic conversion of layered silicate RUB-15 to silica sodalite through interlayer condensation in N-methylformamide. / Koike, Masakazu; Asakura, Yusuke; Sugihara, Megumi; Kuroda, Yoshiyuki; Tsuzura, Hidehiro; Wada, Hiroaki; Shimojima, Atsushi; Kuroda, Kazuyuki.

    In: Dalton Transactions, Vol. 46, No. 31, 2017, p. 10232-10239.

    Research output: Contribution to journalArticle

    Koike, Masakazu ; Asakura, Yusuke ; Sugihara, Megumi ; Kuroda, Yoshiyuki ; Tsuzura, Hidehiro ; Wada, Hiroaki ; Shimojima, Atsushi ; Kuroda, Kazuyuki. / Topotactic conversion of layered silicate RUB-15 to silica sodalite through interlayer condensation in N-methylformamide. In: Dalton Transactions. 2017 ; Vol. 46, No. 31. pp. 10232-10239.
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    AU - Kuroda, Yoshiyuki

    AU - Tsuzura, Hidehiro

    AU - Wada, Hiroaki

    AU - Shimojima, Atsushi

    AU - Kuroda, Kazuyuki

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